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Synthesis of stereochemically and skeletally diverse fused ring systems from functionalized C-glycosides.

ABSTRACT: A diversity-oriented synthesis (DOS) strategy was developed for the synthesis of stereochemically diverse fused-ring systems containing a pyran moiety. Each scaffold contains an amine and methyl ester for further diversification via amine capping and amide coupling. Scaffold diversity was evaluated in comparison to previously prepared scaffolds by a shape-based principal moments of inertia (PMI) analysis.

SUBMITTER: Gerard B 

PROVIDER: S-EPMC3752688 | biostudies-literature | 2013 Jun

REPOSITORIES: biostudies-literature

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A diversity-oriented synthesis (DOS) strategy was developed for the synthesis of stereochemically diverse fused-ring systems containing a pyran moiety. Each scaffold contains an amine and methyl ester for further diversification via amine capping and amide coupling. Scaffold diversity was evaluated in comparison to previously prepared scaffolds by a shape-based principal moments of inertia (PMI) analysis. ...[more]

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