Linear free-energy relationship analysis of a catalytic desymmetrization reaction of a diarylmethane-bis(phenol).
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ABSTRACT:
SUBMITTER: Gustafson JL
PROVIDER: S-EPMC2886716 | biostudies-literature | 2010 Jun
REPOSITORIES: biostudies-literature
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Linear free-energy relationship analysis of a catalytic desymmetrization reaction of a diarylmethane-bis(phenol).
Gustafson Jeffrey L JL Sigman Matthew S MS Miller Scott J SJ
Organic letters 20100601 12
Linear free-energy relationships have been found for enantioselectivity and various steric parameters in an enantioselective desymmetrization of symmetrical bis(phenol) substrates. The potential origin of this observation and the role of different steric parameters are discussed. ...[more]
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