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Comparison of cyanide and carbon monoxide as ligands in iron(II) porphyrinates.

ABSTRACT: Spot the difference: The five-coordinate iron(II) cyanoporphyrinates, which are spin-crossover compounds, can be used to synthesize previously unknown six-coordinate complexes. Bis(cyano) and (cyano)imidazole complexes are presented, and the five- and six-coordinate (cyano)iron(II) derivatives are compared with analogous CO complexes.

SUBMITTER: Li J

PROVIDER: S-EPMC2893548 | biostudies-literature | 2009

REPOSITORIES: biostudies-literature

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Comparison of cyanide and carbon monoxide as ligands in iron(II) porphyrinates.

Li Jianfeng J Noll Bruce C BC Schulz Charles E CE Scheidt W Robert WR

Angewandte Chemie (International ed. in English) 20090101 27

Spot the difference: The five-coordinate iron(II) cyanoporphyrinates, which are spin-crossover compounds, can be used to synthesize previously unknown six-coordinate complexes. Bis(cyano) and (cyano)imidazole complexes are presented, and the five- and six-coordinate (cyano)iron(II) derivatives are compared with analogous CO complexes. ...[more]

PMID: 19492380

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