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Bis(7-amino-2,4-dimethyl-1,8-naphthyridine)dinitratocadmium(II).

ABSTRACT: In the title compound, [Cd(NO(3))(2)(C(10)H(11)N(3))(2)], two naph-thyridine ring systems are coordinated to the Cd ion through the two N atoms in a bidentate chelating mode, whereas the remaining coordination sites are occupied by two O atoms from two different nitrate groups to complete the octahedral geometry. Inter-moleular N-H?O hydrogen bonds link the mol-ecules to form a one-dimensionnal sheet parallel to the ac plane. Weak slipped ?-? stacking involving the naphthyridine ring systems stabilizes the structure.

SUBMITTER: Jin SW

PROVIDER: S-EPMC2914938 | biostudies-literature | 2007

REPOSITORIES: biostudies-literature

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Bis(7-amino-2,4-dimethyl-1,8-naphthyridine)dinitratocadmium(II).

Jin Shou-Wen SW Zhao Qi-Jun QJ Qian Xian-Gang XG Chen Ru-Xiang RX Shi Yan-Fen YF

Acta crystallographica. Section E, Structure reports online 20071206 Pt 1

In the title compound, [Cd(NO(3))(2)(C(10)H(11)N(3))(2)], two naph-thyridine ring systems are coordinated to the Cd ion through the two N atoms in a bidentate chelating mode, whereas the remaining coordination sites are occupied by two O atoms from two different nitrate groups to complete the octahedral geometry. Inter-moleular N-H⋯O hydrogen bonds link the mol-ecules to form a one-dimensionnal sheet parallel to the ac plane. Weak slipped π-π stacking involving the naphthyridine ring systems sta ...[more]

PMID: 21200626

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