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Dichlorido[1-(1-naphthyl-meth-yl)-3-(2-pyrid-yl)-1H-pyrazole-κN,N]palladium(II).

ABSTRACT: In the title compound, [PdCl(2)(C(19)H(15)N(3))], the Pd(II) centre is four-coordinated by two N-atom donors from one 1-[3-(2-pyrid-yl)pyrazol-1-ylmeth-yl]naphthalene (L) ligand and by two Cl atoms in a distorted square-planar coordination geometry. In the crystal structure, adjacent Pd(II) mononuclear units form inter-molecular C-H⋯π inter-actions involving the benzene and pyridine rings of different L ligands and π-π stacking inter-actions between the pyrazolyl-pyridine and naphthalene rings of neighbouring L ligands, with a centroid-centroid separation of 3.522 (1) Å.

SUBMITTER: Liu CS

PROVIDER: S-EPMC2914949 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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Dichlorido[1-(1-naphthyl-meth-yl)-3-(2-pyrid-yl)-1H-pyrazole-κN,N]palladium(II).

Liu Chun-Sen CS Sun Guang-Hui GH Guo Liang-Qi LQ

Acta crystallographica. Section E, Structure reports online 20071206 Pt 1

In the title compound, [PdCl(2)(C(19)H(15)N(3))], the Pd(II) centre is four-coordinated by two N-atom donors from one 1-[3-(2-pyrid-yl)pyrazol-1-ylmeth-yl]naphthalene (L) ligand and by two Cl atoms in a distorted square-planar coordination geometry. In the crystal structure, adjacent Pd(II) mononuclear units form inter-molecular C-H⋯π inter-actions involving the benzene and pyridine rings of different L ligands and π-π stacking inter-actions between the pyrazolyl-pyridine and naphthalene rings o ...[more]

PMID: 21200638

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