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Monoclinic modification of 1,1,3,3,5,5-hexa-methyl-cyclo-1,3,5-tris-tannathiane.


ABSTRACT: The asymmetric unit of the title compound, [Sn(3)(CH(3))(6)S(3)], contains two molecules with twist-boat conformations. There are intermolecular S?H (2.929?Å), S?S (3.433?Å), S?C (3.465?Å) and C?H (2.898?Å) inter-actions in addition to prominent intermolecular Sn?S inter-actions of 3.692 and 3.769?Å.

SUBMITTER: Singh N 

PROVIDER: S-EPMC2915068 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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Monoclinic modification of 1,1,3,3,5,5-hexa-methyl-cyclo-1,3,5-tris-tannathiane.

Singh Nanhai N   Kumar Abhinav A   Molloy Kieran C KC   Kociok-Köhn G G  

Acta crystallographica. Section E, Structure reports online 20071206 Pt 1


The asymmetric unit of the title compound, [Sn(3)(CH(3))(6)S(3)], contains two molecules with twist-boat conformations. There are intermolecular S⋯H (2.929 Å), S⋯S (3.433 Å), S⋯C (3.465 Å) and C⋯H (2.898 Å) inter-actions in addition to prominent intermolecular Sn⋯S inter-actions of 3.692 and 3.769 Å. ...[more]

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