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Tris(1-ethyl-3-methyl-imidazolium) hexa-bromidoeuropate(III).


ABSTRACT: The crystal structure of the title compound, (C(6)H(11)N(2))(3)[EuBr(6)], consists of 1-ethyl-3-methyl-imidazolium cations and centrosymmetric octa-hedral hexa-bromido-europate anions. The [EuBr(6)](3-) anions are located at the corners and face-centres of the monoclinic unit cell. Characteristic hydrogen-bonding inter-actions can be observed between the bromide anions and the acidic H atoms of the imidazolium cations.

SUBMITTER: Pellens M 

PROVIDER: S-EPMC2961749 | biostudies-literature | 2008 Jun

REPOSITORIES: biostudies-literature

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Tris(1-ethyl-3-methyl-imidazolium) hexa-bromidoeuropate(III).

Pellens Michael M   Thijs Ben B   Van Hecke Kristof K   Van Meervelt Luc L   Binnemans Koen K   Nockemann Peter P  

Acta crystallographica. Section E, Structure reports online 20080621 Pt 7


The crystal structure of the title compound, (C(6)H(11)N(2))(3)[EuBr(6)], consists of 1-ethyl-3-methyl-imidazolium cations and centrosymmetric octa-hedral hexa-bromido-europate anions. The [EuBr(6)](3-) anions are located at the corners and face-centres of the monoclinic unit cell. Characteristic hydrogen-bonding inter-actions can be observed between the bromide anions and the acidic H atoms of the imidazolium cations. ...[more]

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