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Benzyl 5-ferrocenyl-3-(4-methyl-phen-yl)-2-pyrazoline-1-dithio-carboxyl-ate.

ABSTRACT: In the title compound, [Fe(C(5)H(5))(C(23)H(21)N(2)S(2))], the cyclo-penta-dienyl rings of the ferrocenyl unit deviate slightly from the eclipsed form. In the pyrazoline ring, the N atom bonded to S-benzyl dithio-carbazate exhibits unconventional sp(2)-hybrid character in order to form an extended conjugated system. The pyrazoline ring displays an envelope conformation. The mol-ecules are linked into chains along the b axis via C-H?S inter-molecular hydrogen bonds.

SUBMITTER: Liu XL

PROVIDER: S-EPMC2915138 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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Benzyl 5-ferrocenyl-3-(4-methyl-phen-yl)-2-pyrazoline-1-dithio-carboxyl-ate.

Liu Xiao-Lan XL Tong Ben-Wan BW Zhao Yue Y Ye Jun J Liu Yong-Hong YH

Acta crystallographica. Section E, Structure reports online 20071218 Pt 1

In the title compound, [Fe(C(5)H(5))(C(23)H(21)N(2)S(2))], the cyclo-penta-dienyl rings of the ferrocenyl unit deviate slightly from the eclipsed form. In the pyrazoline ring, the N atom bonded to S-benzyl dithio-carbazate exhibits unconventional sp(2)-hybrid character in order to form an extended conjugated system. The pyrazoline ring displays an envelope conformation. The mol-ecules are linked into chains along the b axis via C-H⋯S inter-molecular hydrogen bonds. ...[more]

PMID: 21200556

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