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Bis(2-benzoyl-1-phenyl-ethenolato-?O,O')(ethanol-?O)dioxidouranium(VI).

ABSTRACT: In the title compound, [U(C(15)H(11)O(2))(2)O(2)(C(2)H(6)O)], the U(VI )atom has a penta-gonal-bipyramidal coordination geometry. The two so-called '-yl' O atoms occupy the axial positions whereas four O atoms from the two chelating dibenzoyl-methanate ligands and the O atom from the ethanol mol-ecule are situated in the equatorial plane. Inter-molecular hydrogen bonds between one of the '-yl' O atoms and the ethanol OH group assemble mol-ecules into a centrosymmetric dimer.

SUBMITTER: Takao K

PROVIDER: S-EPMC2915146 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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Bis(2-benzoyl-1-phenyl-ethenolato-κO,O')(ethanol-κO)dioxidouranium(VI).

Takao Koichiro K Ikeda Yasuhisa Y

Acta crystallographica. Section E, Structure reports online 20071218 Pt 1

In the title compound, [U(C(15)H(11)O(2))(2)O(2)(C(2)H(6)O)], the U(VI )atom has a penta-gonal-bipyramidal coordination geometry. The two so-called '-yl' O atoms occupy the axial positions whereas four O atoms from the two chelating dibenzoyl-methanate ligands and the O atom from the ethanol mol-ecule are situated in the equatorial plane. Inter-molecular hydrogen bonds between one of the '-yl' O atoms and the ethanol OH group assemble mol-ecules into a centrosymmetric dimer. ...[more]

PMID: 21200566

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