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Bis(trimethyl-phenyl-ammonium) ?-oxalato-bis-[oxidodiperoxido-molybdate(VI)].

ABSTRACT: A trimethyl-phenyl-ammonium salt of a dinuclear ?-oxalate complex of diperoxidomonomolybdate units, (C9H14N)2[Mo2(C2O4)(O2)4O2], was obtained from an acidic aqueous solution; the dianion is located about a centre of inversion. Each Mo atom bears two peroxide groups together with one O atom from the oxalate group in its equatorial positions and one terminal O atom as well as another O atom from the oxalate in axial positions. The oxalate group acts as a tetra-dentate bridging ligand and bridges between the diperoxidomolybdate units.

SUBMITTER: Oba A

PROVIDER: S-EPMC3588729 | biostudies-literature | 2012 Dec

REPOSITORIES: biostudies-literature

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Bis(trimethyl-phenyl-ammonium) μ-oxalato-bis-[oxidodiperoxido-molybdate(VI)].

Oba Ayaka A Hashimoto Masato M

Acta crystallographica. Section E, Structure reports online 20121110 Pt 12

A trimethyl-phenyl-ammonium salt of a dinuclear μ-oxalate complex of diperoxidomonomolybdate units, (C9H14N)2[Mo2(C2O4)(O2)4O2], was obtained from an acidic aqueous solution; the dianion is located about a centre of inversion. Each Mo atom bears two peroxide groups together with one O atom from the oxalate group in its equatorial positions and one terminal O atom as well as another O atom from the oxalate in axial positions. The oxalate group acts as a tetra-dentate bridging ligand and bridges b ...[more]

PMID: 23468694

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