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Di-?-chlorido-bis-[chloridobis(dimethyl sulfoxide)dioxidouranium(VI)].

ABSTRACT: In the crystal structure of the title compound, [U(2)Cl(4)O(4)(C(2)H(6)OS)(4)], the compound has a centrosymmetric dimeric structure bridged by two chloride anions. Each U(VI) atom is seven-coordinate in a penta-gonal-bipyramidal geometry. In the equatorial plane of the uranyl unit there are two O atoms from non-adjacent dimethyl sulfoxides and three chloride ions (of which two chlorides are bridging). The compound is of inter-est as an anhydrous starting material of the uran-yl(VI) ion.

SUBMITTER: Takao K

PROVIDER: S-EPMC2915060 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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Di-μ-chlorido-bis-[chloridobis(dimethyl sulfoxide)dioxidouranium(VI)].

Takao Koichiro K Ikeda Yasuhisa Y

Acta crystallographica. Section E, Structure reports online 20071206 Pt 1

In the crystal structure of the title compound, [U(2)Cl(4)O(4)(C(2)H(6)OS)(4)], the compound has a centrosymmetric dimeric structure bridged by two chloride anions. Each U(VI) atom is seven-coordinate in a penta-gonal-bipyramidal geometry. In the equatorial plane of the uranyl unit there are two O atoms from non-adjacent dimethyl sulfoxides and three chloride ions (of which two chlorides are bridging). The compound is of inter-est as an anhydrous starting material of the uran-yl(VI) ion. ...[more]

PMID: 21200466

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