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Poly[?(3)-aqua-?(2)-2,4-dinitro-phenolato-rubidium(I)].

ABSTRACT: The asymmetric unit of the title compound, [Rb(C(6)H(3)N(2)O(5))(H(2)O)](n), comprises a rubidium cation, a 2,4-dinitro-phenoxide anion and a water mol-ecule. The Rb(+) cation is 11-coordinated by O atoms from 2,4-dinitro-phenolate anions and water mol-ecules. The metal centre is firstly coordinated by two ?(3)-H(2)O to form a one-dimensional ladder-shaped unit, [Rb(2)(?(3)-H(2)O)(2)], which is further linked by 2,4-dinitro-phenolate to give the three-dimensional framework of the title compound. The crystal structure involves O-H?O hydrogen bonds.

SUBMITTER: Yang Z

PROVIDER: S-EPMC2915150 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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Poly[μ(3)-aqua-μ(2)-2,4-dinitro-phenolato-rubidium(I)].

Yang Zhangqin Z Hu Mancheng M Wang Xiuhang X

Acta crystallographica. Section E, Structure reports online 20071221 Pt 1

The asymmetric unit of the title compound, [Rb(C(6)H(3)N(2)O(5))(H(2)O)](n), comprises a rubidium cation, a 2,4-dinitro-phenoxide anion and a water mol-ecule. The Rb(+) cation is 11-coordinated by O atoms from 2,4-dinitro-phenolate anions and water mol-ecules. The metal centre is firstly coordinated by two μ(3)-H(2)O to form a one-dimensional ladder-shaped unit, [Rb(2)(μ(3)-H(2)O)(2)], which is further linked by 2,4-dinitro-phenolate to give the three-dimensional framework of the title compound. ...[more]

PMID: 21200571

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