Unknown

Dataset Information

0

Diaqua-bis(2,4-dichloro-6-formyl-phenolato)zinc(II)-bis-(?-2,4-dichloro-6-formyl-phenolato)bis-[aqua-(2,4-dichloro-6-formyl-phenolato)zinc(II)] (2/1).

ABSTRACT: The crystal of the title compound, [Zn(C(7)H(3)Cl(2)O(2))(2)(H(2)O)(2)](2)·[Zn(2)(C(7)H(3)Cl(2)O(2))(4)(H(2)O)(2)], consists of monomeric and dimeric Zn(II) complexes. Both complexes afford a six-coordinated coordination environment about the Zn atoms with cis-configuration ligands. The deprotonated hydr-oxy groups of the 3,5-dichloro-salicylaldehyde ligands bridge two metal cations, forming a centrosymmetric dimeric complex. Inter-molecular O-H?O hydrogen bonding occurs between the coordinated water mol-ecules and deprotonated hydr-oxy groups in the crystal structure.

SUBMITTER: Watanabe Y 

PROVIDER: S-EPMC2972068 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Diaqua-bis(2,4-dichloro-6-formyl-phenolato)zinc(II)-bis-(μ-2,4-dichloro-6-formyl-phenolato)bis-[aqua-(2,4-dichloro-6-formyl-phenolato)zinc(II)] (2/1).

Watanabe Yoshimasa Y   Aritake Yoshikazu Y   Akitsu Takashiro T  

Acta crystallographica. Section E, Structure reports online 20091121 Pt 12

The crystal of the title compound, [Zn(C(7)H(3)Cl(2)O(2))(2)(H(2)O)(2)](2)·[Zn(2)(C(7)H(3)Cl(2)O(2))(4)(H(2)O)(2)], consists of monomeric and dimeric Zn(II) complexes. Both complexes afford a six-coordinated coordination environment about the Zn atoms with cis-configuration ligands. The deprotonated hydr-oxy groups of the 3,5-dichloro-salicylaldehyde ligands bridge two metal cations, forming a centrosymmetric dimeric complex. Inter-molecular O-H⋯O hydrogen bonding occurs between the coordinated  ...[more]

Similar Datasets

Unknown cis-Aqua-bis(2,4-dichloro-6-formyl-phenolato-κO,O')(N,N-dimethyl-formamide-κO)nickel(II).
| S-EPMC2961979 | biostudies-literature
Unknown catena-Poly[copper(II)-bis(μ-2,4-dichloro-6-formyl-phenolato)-κO,O':Cl;κCl:O,O'].
| S-EPMC2961934 | biostudies-literature
Unknown Bis(2,4-dibromo-6-formyl-phenolato-κO,O')copper(II).
| S-EPMC2914936 | biostudies-literature
Unknown Diaqua-bis(4-bromo-2-formyl-phenolato-?O,O')cobalt(II).
| S-EPMC2959384 | biostudies-literature
Unknown Tetra-aqua-bis[2-(2,4-dichloro-phen-oxy)acetato]nickel(II).
| S-EPMC2969976 | biostudies-literature
Unknown Poly[diaqua-bis[?(2)-2,4-(dichloro-phenoxy)-acetato-?O:O']iron(II)].
| S-EPMC2959489 | biostudies-literature
Unknown Poly[[diaqua-bis[μ-(2,4-dichloro-phen-oxy)acetato]calcium(II)] monohydrate].
| S-EPMC2961213 | biostudies-literature
Unknown Diaqua-bis(3,7-dichloro-quinoline-8-carboxyl-ato)zinc(II) monohydrate.
| S-EPMC2960553 | biostudies-literature
Unknown Bis[2,4-dichloro-6-(ethyl-imino-meth-yl)phenolato-?N,O]nickel(II).
| S-EPMC3247532 | biostudies-literature
Unknown Diaqua-bis(4-formyl-benzoato-?O)zinc(II).
| S-EPMC2960827 | biostudies-other