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2,2-Dichloro-N-(2,3-dimethyl-phen-yl)acetamide.


ABSTRACT: The conformation of the N-H bond in the title compound, C(10)H(11)Cl(2)NO, is syn to both the 2- and 3-methyl substituents in the aromatic ring, similar to that of the 2-chloro and 3-chloro substituents in 2,2-dichloro-N-(2,3-dichloro-phen-yl)acetamide and the 2-methyl substituent in 2,2-dichloro-N-(2-methyl-phen-yl)acetamide, but in contrast to the anti conformation observed with respect to the 3-methyl substituent in 2,2-dichloro-N-(3-methyl-phen-yl)acetamide. The bond parameters in the title compound are similar to those in 2,2-dichloro-N-phenyl-acetamide and other acetanilides. The mol-ecules of the title compound are linked into chains through N-H?O and C-H?O hydrogen bonding.

SUBMITTER: Gowda BT 

PROVIDER: S-EPMC2915294 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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2,2-Dichloro-N-(2,3-dimethyl-phen-yl)acetamide.

Gowda B Thimme BT   Svoboda Ingrid I   Foro Sabine S   Paulus Helmut H   Fuess Hartmut H  

Acta crystallographica. Section E, Structure reports online 20071212 Pt 1


The conformation of the N-H bond in the title compound, C(10)H(11)Cl(2)NO, is syn to both the 2- and 3-methyl substituents in the aromatic ring, similar to that of the 2-chloro and 3-chloro substituents in 2,2-dichloro-N-(2,3-dichloro-phen-yl)acetamide and the 2-methyl substituent in 2,2-dichloro-N-(2-methyl-phen-yl)acetamide, but in contrast to the anti conformation observed with respect to the 3-methyl substituent in 2,2-dichloro-N-(3-methyl-phen-yl)acetamide. The bond parameters in the title  ...[more]

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