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Aziridinomitosanes via lactam cyclization.


ABSTRACT: Aziridinomitosane ketones 4 and 24 are accessed by internal acyl anion equivalent-lactam cyclization of 29 in a convergent route. The key aziridinolactam 6 is prepared by tin-lithium exchange via the lithiated aziridine 11.

SUBMITTER: Wiedner SD 

PROVIDER: S-EPMC2946824 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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Aziridinomitosanes via lactam cyclization.

Wiedner Susan D SD   Vedejs Edwin E  

Organic letters 20100901 18


Aziridinomitosane ketones 4 and 24 are accessed by internal acyl anion equivalent-lactam cyclization of 29 in a convergent route. The key aziridinolactam 6 is prepared by tin-lithium exchange via the lithiated aziridine 11. ...[more]

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