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Catena-Poly[[(2,2'-bipyridine-?N,N')nickel(II)]-?-oxalato-?O,O:O,O].

ABSTRACT: The title compound, [Ni(C(2)O(4))(C(10)H(8)N(2))](n), is isostructural with its Mn(II), Fe(II), Cu(II) and Zn(II) analogues. Each Ni(II) atom is chelated by two oxalate ligands and one 2,2'-bipyridine, forming a slightly distorted octa-hedral geometry. Oxlate acts as a bridge to link neighbouring pairs of Ni(II) cations, forming a one-dimensional wave-like chain. The crystal showed partial inversion twinning.

SUBMITTER: Li S 

PROVIDER: S-EPMC2959270 | biostudies-literature | 2008 Sep

REPOSITORIES: biostudies-literature

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catena-Poly[[(2,2'-bipyridine-κN,N')nickel(II)]-μ-oxalato-κO,O:O,O].

Li Sheng S   Yan Xing-Lian XL   Wang Shou-Bin SB   Ma Yuan-Fang YF  

Acta crystallographica. Section E, Structure reports online 20080913 Pt 10

The title compound, [Ni(C(2)O(4))(C(10)H(8)N(2))](n), is isostructural with its Mn(II), Fe(II), Cu(II) and Zn(II) analogues. Each Ni(II) atom is chelated by two oxalate ligands and one 2,2'-bipyridine, forming a slightly distorted octa-hedral geometry. Oxlate acts as a bridge to link neighbouring pairs of Ni(II) cations, forming a one-dimensional wave-like chain. The crystal showed partial inversion twinning. ...[more]

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