Unknown

Dataset Information

0

Catena-Poly[[aqua-(5,5'-dimethyl-2,2'-bipyridine-?N,N')copper(II)]-?-2,2'-oxydibenzoato-?O:O'].

ABSTRACT: In the title compound, [Cu(C(14)H(8)O(5))(C(12)H(12)N(2))(H(2)O)](n), the Cu(II) ion is penta-coordinated in a square-pyramidal geometry. Two N atoms of the chelating 5,5'-dimethyl-2,2'-bipyridine (dbp) ligand and two O atoms of two different 2,2'-oxydibenzoic (odb) ligands occupy the basal plane while the water O atom completes the square-pyramidal geometry at the apical site. The non-water N(2)O(2) donor atoms are nearly coplanar, with a mean deviation from the least-squares plane of 0.0518?(11)?Å and the Cu atom is displaced by 0.1507?(11)?Å from this plane towards the apical water O atom. Further coordination via the 2,2'-oxydibenzoate anions forms a one-dimensional coordination polymer extending parallel to [010]. In the crystal structure, O-H?O hydrogen bonds link the mol-ecules into a two-dimensional supra-molecular structure.

SUBMITTER: Mei CZ 

PROVIDER: S-EPMC3007526 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

catena-Poly[[aqua-(5,5'-dimethyl-2,2'-bipyridine-κN,N')copper(II)]-μ-2,2'-oxydibenzoato-κO:O'].

Mei Chong-Zhen CZ   Xiong Han-Lin HL   Zhang Peng P  

Acta crystallographica. Section E, Structure reports online 20100710 Pt 8

In the title compound, [Cu(C(14)H(8)O(5))(C(12)H(12)N(2))(H(2)O)](n), the Cu(II) ion is penta-coordinated in a square-pyramidal geometry. Two N atoms of the chelating 5,5'-dimethyl-2,2'-bipyridine (dbp) ligand and two O atoms of two different 2,2'-oxydibenzoic (odb) ligands occupy the basal plane while the water O atom completes the square-pyramidal geometry at the apical site. The non-water N(2)O(2) donor atoms are nearly coplanar, with a mean deviation from the least-squares plane of 0.0518 (1  ...[more]

Similar Datasets

Unknown catena-Poly[[(5,5'-dimethyl- 2,2'-bipyridine-?N,N')cadmium(II)]-di-?-chlorido].
| S-EPMC2959444 | biostudies-literature
Unknown catena-Poly[[(2,2'-bipyridine)-nickel(II)]-?-2,4'-oxydibenzoato].
| S-EPMC3011413 | biostudies-other
Unknown catena-Poly[[(5,5'-dimethyl-2,2'-bipyridine-?(2)N,N')cadmium]-di-?-bromido].
| S-EPMC3379185 | biostudies-literature
Unknown Tetra-aqua-(5,5'-dimethyl-2,2'-bipyridine-?N,N')zinc(II) sulfate.
| S-EPMC2977444 | biostudies-literature
Unknown catena-Poly[[tetra-aqua-cobalt(II)]-μ-2,2'-dihydroxy-5,5'-diazenediyldibenzoato].
| S-EPMC2960221 | biostudies-literature
Unknown Aqua-bis(benzoato-?O)(5,5'-dimethyl-2,2'-bipyridine-?N,N')copper(II).
| S-EPMC2971325 | biostudies-other
Unknown catena-Poly[[aqua-(2,2'-bipyridine-κN,N')copper(II)]-μ-5-nitro-isophthalato-κO,O:O].
| S-EPMC2959803 | biostudies-literature
Unknown catena-Poly[[tetra-aqua-zinc(II)]-μ-2,2'-dihydr-oxy-5,5'-diazenediyldibenzoato].
| S-EPMC2960379 | biostudies-literature
Unknown catena-Poly[[(2,2'-bipyridine)copper(II)]-μ-5-tert-butyl-isophthalato].
| S-EPMC2960003 | biostudies-literature
Unknown 5,5'-Dimethyl-2,2'-bipyridine.
| S-EPMC2969272 | biostudies-literature