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Crystal structure of benzyl-tri-phenyl-phospho-nium chloride monohydrate.


ABSTRACT: The title compound, Ph3(PhCH2)P(+)·Cl(-)·H2O, was obtained unintentionally as the product of an attempted synthesis of a silver di-thio-carbamate complex using benzyl-tri-phenyl-phospho-nium as the counter-ion. The asymmetric unit consists of a phospho-nium cation and a chloride anion, and a water mol-ecule of crystallization. In the crystal, the chloride ion is linked to the water mol-ecule by an O-H?Cl hydrogen bond. The three units are further linked via C-H?Cl and C-H?O hydrogen bonds and C-H? ? inter-actions, forming a three-dimensional structure.

SUBMITTER: Ahmad J 

PROVIDER: S-EPMC4459357 | biostudies-literature | 2015 Jun

REPOSITORIES: biostudies-literature

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Crystal structure of benzyl-tri-phenyl-phospho-nium chloride monohydrate.

Ahmad Jimmy J   Abdul Halim Siti Nadiah SN   How Fiona N-F FN  

Acta crystallographica. Section E, Crystallographic communications 20150520 Pt 6


The title compound, Ph3(PhCH2)P(+)·Cl(-)·H2O, was obtained unintentionally as the product of an attempted synthesis of a silver di-thio-carbamate complex using benzyl-tri-phenyl-phospho-nium as the counter-ion. The asymmetric unit consists of a phospho-nium cation and a chloride anion, and a water mol-ecule of crystallization. In the crystal, the chloride ion is linked to the water mol-ecule by an O-H⋯Cl hydrogen bond. The three units are further linked via C-H⋯Cl and C-H⋯O hydrogen bonds and C-  ...[more]

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