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Bis[?-3-(1H-pyrazol-1-yl)benzonitrile-?N:N']bis-[perchloratosilver(I)].

ABSTRACT: In the title centrosymmetric complex, [Ag(2)(ClO(4))(2)(C(10)H(7)N(3))(2)], the unique Ag(I) ion is coordinated by an N atom from a carbonitrile group, an N atom from a symmetry-related pyrazole group and an O atom of a perchlorate ligand to form a distorted T-shaped environment. Two 3-(1H-pyrazol-1-yl)benzonitrile ligands each bridge two Ag(I) ions to form a dinuclear complex. In the crystal structure, there are weak Ag?O inter-actions within the range 2.70-3.01?Å linking dimeric units into layers approximately parallel to (100). The O atoms of the perchlorate ligand are disordered over two sites with occupancies of 0.570?(11) and 0.430?(11), respectively.

SUBMITTER: Niu CY 

PROVIDER: S-EPMC2959349 | biostudies-literature | 2008 Sep

REPOSITORIES: biostudies-literature

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Bis[μ-3-(1H-pyrazol-1-yl)benzonitrile-κN:N']bis-[perchloratosilver(I)].

Niu Cao-Yuan CY   Zhang Hai-Yan HY   Feng Cao-Ling CL   Wan Xin-Sheng XS   Kou Chun-Hong CH  

Acta crystallographica. Section E, Structure reports online 20080927 Pt 10

In the title centrosymmetric complex, [Ag(2)(ClO(4))(2)(C(10)H(7)N(3))(2)], the unique Ag(I) ion is coordinated by an N atom from a carbonitrile group, an N atom from a symmetry-related pyrazole group and an O atom of a perchlorate ligand to form a distorted T-shaped environment. Two 3-(1H-pyrazol-1-yl)benzonitrile ligands each bridge two Ag(I) ions to form a dinuclear complex. In the crystal structure, there are weak Ag⋯O inter-actions within the range 2.70-3.01 Å linking dimeric units into lay  ...[more]

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