Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

(R)-N-{2-tert-Butyl-2-[(R)-tert-butyl-sulfonamido]ethylidene}-tert-butane-sulfonamide.

ABSTRACT: The title compound, C(14)H(30)N(2)O(2)S(2), is the product of the monoaddition reaction of tert-butyl magnesium chloride with bis-[(R)-N-tert-butanesulfinyl]ethanediimine. There are two almost identical mol-ecules in the asymmetric unit, the mol-ecular conformation of which is stabilized by an intra-molecular N-H?N hydrogen bond.

SUBMITTER: Hu Y

PROVIDER: S-EPMC2959383 | biostudies-literature | 2008 Sep

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

(R)-N-{2-tert-Butyl-2-[(R)-tert-butyl-sulfonamido]ethylidene}-tert-butane-sulfonamide.

Hu Yu Y Sun Xiao-Xia XX Fan Cong-Bin CB

Acta crystallographica. Section E, Structure reports online 20080913 Pt 10

The title compound, C(14)H(30)N(2)O(2)S(2), is the product of the monoaddition reaction of tert-butyl magnesium chloride with bis-[(R)-N-tert-butanesulfinyl]ethanediimine. There are two almost identical mol-ecules in the asymmetric unit, the mol-ecular conformation of which is stabilized by an intra-molecular N-H⋯N hydrogen bond. ...[more]

PMID: 21201122

Similar Datasets

tert-Butyl 2-hy-droxy-3-(4-methyl-benzene-sulfonamido)-butano-ate.

Project description:In the crystal of the title compound, C(15)H(23)NO(5)S, mol-ecules are linked through N-H⋯O and O-H⋯O hydrogen-bond inter-actions, resulting in centrosymmetric dimers in which the N-H⋯O inter-actions generate R(2) (2)(12) rings and the O-H⋯O inter-actions generate R(2) (2)(14) rings. Weak inter-molecular C-H⋯O inter-actions are also observed.

| S-EPMC3052123 | biostudies-literature

1,2-Di-tert-butyl-ethane-1,2-diyl bis-(tert-butane-sulfinamide).

Project description:In the title compound, C(18)H(40)N(2)O(2)S(2), a vicinal diamine derivative, the crystal structure is stabilized by two intra-molecular N-H?O hydrogen bonds. The distance between the two kernel chiral C atoms is 1.580?(2)?Å.

| S-EPMC2968083 | biostudies-other

tert-Butyl N-[2-(N-isobutyl-4-meth-oxy-benzene-sulfonamido)-eth-yl]carbamate.

Project description:The title compound, C18H30N2O5S, was synthesized by the reaction of tert-butyl 2-(iso-butyl-amino)-ethyl-carbamate with p-meth-oxy-phenyl-sulfonyl chloride. In the mol-ecule, two intra-molecular C-H?O hydrogen bonds are observed. In the crystal, mol-ecules are linked by N-H?O hydrogen bonds involving the imino group N atom and the ester group O atom into chains running parallel to the b axis. The chains are further connected by C-H?O hydrogen bonds, forming layers parallel to the bc plane.

| S-EPMC4051064 | biostudies-literature

4,4',6,6'-Tetra-tert-butyl-2,2'-[butane-1,4-diylbis(nitrilo-methanylyl-idene)]diphenol.

Project description:The title compound, C(34)H(52)N(2)O(2), is centrosymmetric, the mid-point of the central C-C bond being located on an inversion centre. Intra-molecular O-H⋯N and weak C-H⋯O hydrogen bonds are observed, but no significant inter-molecular inter-actions occur in the crystal structure.

| S-EPMC3247362 | biostudies-literature

Crystal structure of 2,3-bis-[(4-tert-butyl-2,6-di-methyl-phen-yl)imino]-butane.

Project description:The title compound, C28H40N2, was obtained from the condensation reaction of 4-tert-butyl-2,6-di-methyl-aniline and butane-2,3-dione. The mol-ecule lies on an inversion centre. The C=N bond has an E conformation. The plane of the benzene ring is almost perpendicular to the 1,4-di-aza-butadiene mean plane [dihedral angle = 89.8 (9)°].

| S-EPMC4438850 | biostudies-literature

N-Acetyl-4-(benzene-sulfonamido)benzene-sulfonamide.

Project description:In the mol-ecule of the title compound, C(14)H(14)N(2)O(5)S(2), the dihedral angle between the aromatic rings is 77.75 (9)°. The acetamide group is planar [maximum deviation = 0.002 (3) Å] and oriented at dihedral angles of 13.49 (21) and 73.94 (10)° with respect to the aromatic rings. An intra-molecular C-H⋯O inter-action results in the formation of a six-membered ring. In the crystal structure, inter-molecular N-H⋯O and C-H⋯O inter-actions link the mol-ecules into a three-dimensional network, forming R(2) (2)(20) ring motifs.

| S-EPMC2977844 | biostudies-literature

N-Phenyl-tert-butane-sulfinamide.

Project description:In the racemic title compound, C(10)H(15)NOS, the packing exhibits centrosymmetric pairs of mol-ecules linked by N-H?O=S hydrogen bonds in a head-to-tail fashion. The N-C(ar-yl) bond [1.4083?(12)?Å] is considerably shorter than the N-C(alk-yl) bonds typically found in N-alkyl-alkanesulfinamides (1.470-1.530?Å).

| S-EPMC2977387 | biostudies-literature

4-tert-Butyl-pyridinium triiodide-4-tert-butyl-pyridine (1/1).

Project description:The title compound, C(9)H(14)N(+)·I(3) (-)·C(9)H(13)N, consists of monoprotonated 4-tert-butyl-pyridinium cations and triiodide anions. The triiodide ion has near-symmetric linear geometry, with bond lengths of 2.9105 (4) Å (I-I) and a bond angle of 177.55 (3)° (I-I-I). For this room-temperature structure, the butyl group on the pyridine ring is disordered and has been treated as a rigid rotator, modeled in three separate positions with 1/3, 1/3, 1/3 occupancies. The cations assemble into dimeric forms by way of N-H⋯N hydrogen bonds.

| S-EPMC3051785 | biostudies-literature

Butyl 4-(4-methyl-benzene-sulfonamido)-benzoate.

Project description:In the title compound, C(18)H(21)NO(4)S, the aromatic rings are almost normal to each other, with a dihedral angle of 89.27 (18)°. The mol-ecular conformation is stabilized by an intra-molecular C-H⋯O inter-action, which generates an S(6) motif. In the crystal, N-H⋯O and C-H⋯O hydrogen bonds lead to the formation of chains propagating along [010]. Neighbouring chains are linked via a C-H⋯π inter-action. The -CH(2)CH(2)CH(3) atoms of the butyl group are disordered over two sets of sites, with a refined site-occupancy ratio of 0.536 (16):0.464 (16).

| S-EPMC3344642 | biostudies-literature

N-[3-(Benzene-sulfonamido)-prop-yl]benzene-sulfonamide.

Project description:In the title compound, C(15)H(18)N(2)O(4)S(2), the dihedral angle between the aromatic rings is 71.8?(2)°. The conformation of the central N-C-C-C-N fragment is gauche-gauche [torsion angles = 72.5?(5) and 65.7?(5)°]. Both N atoms adopt pyramidal geometries. In the crystal, mol-ecules are linked by N-H?O hydrogen bonds, generating (001) sheets, and weak C-H?O inter-actions consolidate the packing.

| S-EPMC3151767 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data