Ontology highlight
ABSTRACT:
SUBMITTER: Xu ZL
PROVIDER: S-EPMC2959433 | biostudies-literature | 2008 Sep
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20080906 Pt 10
In the title compound, [Fe(C(6)H(2)N(2)O(4))(C(18)H(10)N(4))(H(2)O)](n), the Fe(II) ion adopts a slightly distorted octahedral mer-FeN(3)O(3) geometry, arising from one N,N'-bidentate dipyrido[3,2-a:2',3'-c]phenazine ligand, one N,O-chelating pyrazine-2,3-dicarboxyl-ate dianion and one water mol-ecule. An O-bonded symmetry-related dianion completes the coordination of the metal. The bridging dianion results in a one-dimensional polymeric chain. Aromatic π-π stacking inter-actions between ligands ...[more]