Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

1-Benzoyl-N-phenyl-cyclo-propane-carboxamide.

ABSTRACT: The title compound, C(17)H(15)NO(2), was synthesized by reaction of 1,2-dibromo-ethane with 1-benzoyl-N-phenyl-cyclo-propane-carboxamide and K(2)CO(3) in dimethyl-formamide. The mol-ecule exhibits a V-shaped conformation in the crystal with a dihedral angle of 88.7?(3)° between the two benzene rings. Pairs of N-H?O hydrogen bonds link the mol-ecules into dimers about centres of inversion.

SUBMITTER: Li WL

PROVIDER: S-EPMC2959514 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

1-Benzoyl-N-phenyl-cyclo-propane-carboxamide.

Li Wen-Liang WL Zhu Zhi-Guo ZG

Acta crystallographica. Section E, Structure reports online 20081025 Pt 11

The title compound, C(17)H(15)NO(2), was synthesized by reaction of 1,2-dibromo-ethane with 1-benzoyl-N-phenyl-cyclo-propane-carboxamide and K(2)CO(3) in dimethyl-formamide. The mol-ecule exhibits a V-shaped conformation in the crystal with a dihedral angle of 88.7 (3)° between the two benzene rings. Pairs of N-H⋯O hydrogen bonds link the mol-ecules into dimers about centres of inversion. ...[more]

PMID: 21581038

Similar Datasets

1-Cyano-N-(2,4,5-trichloro-phen-yl)cyclo-propane-1-carboxamide.

Project description:In the title compound, C(11)H(7)Cl(3)N(3)O, the dihedral angle between the benzene and cyclo-propane rings is 85.8?(2)°. In the crystal, mol-ecules are linked by C-H?O inter-actions, generating C(5) chains propagating in the a-axis direction.

| S-EPMC3212327 | biostudies-literature

(1R,3S)-3-Hydroxy-meth-yl-N-isopropyl-2,2-dimethyl-cyclo-propane-carboxamide.

Project description:The asymmetric unit of the title compound, C(10)H(19)NO(2), prepared from (-)-1R-cis-caronaldehyde, contains two independent mol-ecules. In the crystal structure, inter-molecular O-H?O and O-H?N hydrogen bonds form an extensive three-dimensional hydrogen-bonding network.

| S-EPMC2980056 | biostudies-literature

2-Amino-pyridinium 1-phenyl-cyclo-propane-1-carboxyl-ate.

Project description:In the title salt, C(5)H(7)N(2) (+)·C(10)H(9)O(2) (-), 2-amino-pyridine and 1-phenyl-cyclo-propane-1-carb-oxy-lic acid crystallize together, forming a 2-amino-pyridinium-carboxyl-ate supra-molecular heterosynthon involving two N-H?O hydrogen bonds, which in turn dimerizes to form a four-component supra-molecular unit also sustained by N-H?O hydrogen bonding. A C-H?? inter-action between a pyridine C-H group and the centroid of the phenyl ring of the anion further stabilizes the four-component supra-molecular unit. The overall crystal packing also features C-H?O inter-actions.

| S-EPMC3011640 | biostudies-literature

1-[1-(Hydroxy-imino)eth-yl]-N-(2-methoxy-phen-yl)cyclo-propane-carboxamide.

Project description:The title compound, C(13)H(16)N(2)O(3), adopts an E configuration with respect to the C=N bond and an intra-molecular N-H?N hydrogen bond results in the formation of a six-membered ring. In the crystal, inter-molecular O-H?O hydrogen bonds link the mol-ecules into a chain propagating along the b axis. Very weak ?-? stacking inter-actions [centroid-centroid distance = 4.18?(2)?Å] may further consolidate the packing, forming a two-dimensional supra-molecular network.

| S-EPMC2969475 | biostudies-literature

(N-Benzoyl-N'-phenyl-thio-urea-?S)chlorido(?-1,5-cyclo-octa-diene)rhodium(I).

Project description:The title compound, [RhCl(C(8)H(12))(C(14)H(12)N(2)OS)], is a rhodium(I) derivative with a functionalized thio-urea ligand. Despite the presence of several heteroatoms, the thio-urea ligand coordinates only in a monodentate fashion via the S atom. The geometry of the coordination sphere is approximately square planar about the Rh(I) atom, with two bonds to the ?-electrons of the 1,5-cyclo-octa-diene ligand, one bond to the Cl(-) ligand and one bond to the S atom of the thio-urea ligand. The mol-ecular structure is stabilized by intra-molecular N-H?O and N-H?Cl hydrogen bonding. Inter-molecular N-H?O hydrogen-bonding inter-actions lead to the formation of layers extending parallel to (011).

| S-EPMC3007502 | biostudies-literature

Methyl c-1-cyano-t-2-methyl-sulfonyl-3-phenyl-cyclo-propane-carboxyl-ate.

Project description:The title compound, C(13)H(13)NO(4)S, is a racemic mixture of enanti-omers. Short intra-molecular contacts between sulfonyl O and ester carbonyl C atoms are observed [C?O = 2.881?(1), 2.882?(1) and 2.686?(1) Å], indicating the possibility of donor-acceptor inter-actions between these groups. The dihedral angle between the phenyl and cyclopropyl rings is 79.3?(1)°.

| S-EPMC3120552 | biostudies-literature

4-Isopropyl-N-phenyl-cyclo-hexa-1,3-diene-1-carboxamide.

Project description:In the crystal structure of the title compound, C(16)H(19)NO, mol-ecules are linked through a pair of N-H?O hydrogen bonds, forming chains along the a axis.

| S-EPMC2983390 | biostudies-other

(E)-3-(2-Chloro-3,3,3-trifluoro-prop-1-en-yl)-2,2-dimethyl-N,N-diphenyl-cyclo-propane-carboxamide.

Project description:The title compound, C(21)H(19)ClF(3)NO, was synthesized from 3-[(E)-2-chloro-3,3,3-trifluoro-prop-1-en-yl]-2,2-dimethyl-cyclo-propane-carboxylic acid and diphenyl-amine. The propenyl and carboxamide substituents lie on the same side of the cyclo-propane ring plane, with the two methyl substituents on either side of the plane. The phenyl rings of the carboxamide are inclined at an angle of 84.6 (3)° to one another. The F atoms are disordered over two positions; the site occupancy factors are ca 0.6 and 0.4.

| S-EPMC2914980 | biostudies-literature

(E)-3-(2-Chloro-3,3,3-trifluoro-prop-1-en-yl)-2,2-dimethyl-N-p-tolyl-cyclo-propane-carboxamide.

Project description:There are two mol-ecules in the asymmetric unit of the title compound, C(16)H(17)ClF(3)NO. The benzene ring in each mol-ecule makes a dihedral angle of 66.6 (3)° [116.3 (4)° in the second mol-ecule] with the plane of the cyclo-propane ring. The F atoms of the CF(3) groups are disordered equally over two positions. The amide hydrogen is linked with the amide oxygen in another mol-ecule by an inter-molecular N-H⋯O hydrogen bond. The packing can be described as a dimeric arrangement of mol-ecules linked through N-H⋯O hydrogen bonds.

| S-EPMC2960375 | biostudies-literature

(E)-3-(2-Chloro-3,3,3-trifluoro-prop-1-en-yl)-2,2-dimethyl-N-(2-naphth-yl)cyclo-propane-carboxamide.

Project description:The title compound, C(19)H(17)ClF(3)NO, was synthesized from 3-[(E)-2-chloro-3,3,3-trifluoro-prop-1-en-yl]-2,2-dimethyl-cyclopropane-carboxylic acid and 2-aminona-phthalene. There are two molecules in the asymmetric unit. The dihedral angle between the naphthalene and cyclo-propane units is 111.6?(5)°. Molecules are connected into chains by intermol-ecular N-H?O hydrogen bonds. One of the Cl atoms is disordered over two positions with occupancies 0.653?(15) and 0.347?(15).

| S-EPMC2959779 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data