Browse
Submit Data
Databases
API
Help

Dataset Information

19 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Diethyl-ammonium anilino(meth-oxy)-phosphinate.

ABSTRACT: The title compound, [Et(2)NH(2)][(EtO)PO(2)(C(6)H(5)NH)] or C(4)H(12)N(+)·C(8)H(11)NO(3)P(-), is a molecular salt with two anions containing PO(3)N groupings and two cations in the asymmetric unit. A network of N-H?O hydrogen bonds link the cations and anions into a two-dimensional network.

SUBMITTER: Fu Z

PROVIDER: S-EPMC2959537 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Diethyl-ammonium anilino(meth-oxy)-phosphinate.

Fu Zhiyong Z Liu Xiaoling X

Acta crystallographica. Section E, Structure reports online 20081022 Pt 11

The title compound, [Et(2)NH(2)][(EtO)PO(2)(C(6)H(5)NH)] or C(4)H(12)N(+)·C(8)H(11)NO(3)P(-), is a molecular salt with two anions containing PO(3)N groupings and two cations in the asymmetric unit. A network of N-H⋯O hydrogen bonds link the cations and anions into a two-dimensional network. ...[more]

PMID: 21581031

Similar Datasets

2-[(4-Meth-oxy-anilino)meth-yl]phenol.

Project description:In the title compound, C(14)H(15)NO(2), the dihedral angle between the two benzene rings is 71.10 (5)°. In the crystal, mol-ecules are linked by inter-molecular N-H⋯O, and O-H⋯N hydrogen bonds into a chain running parallel to the b axis.

| S-EPMC3200731 | biostudies-literature

Diisopropyl-ammonium 4-meth-oxy-benzoate.

Project description:In the crystal structure of the title compound, C(6)H(16)N(+)·C(8)H(7)O(3) (-), inter-molecular N-H?O hydrogen bonds link the cations and anions into arrangements consisting of two cations and two anions each.

| S-EPMC3152061 | biostudies-literature

Ammonium 4-meth-oxy-benzene-sulfonate.

Project description:The mol-ecular structure of the title compound, NH(4) (+)·C(7)H(7)O(4)S(-), is featureless [the methoxy C atom deviating 0.173 (6) Å from the phenyl mean plane] with inter-atomic distances and angles in the expected ranges. The main feature of inter-est is the packing mode. Hydro-philic (SO(3) and NH(4)) and hydro-phobic (PhOCH(3)) parts in the structure segregate, the former inter-acting through a dense hydrogen-bonding scheme, leading to a well connected two-dimensional structure parallel to (100) and the latter hydro-phobic groups acting as spacers for an inter-planar separation of c/2 = 10.205 (2) Å. In spite of being aligned along [110], the benzene rings stack in a far from parallel fashion [viz. consecutive ring centers determine a broken line with a 164.72 (12)° zigzag angle], thus preventing any possible π-π inter-action.

| S-EPMC3394020 | biostudies-literature

Diethyl [(9-anthr-yl)(4-methyl-anilino)meth-yl]phospho-nate.

Project description:The title compound, C(26)H(28)NO(3)P, crystallized with two independent mol-ecules in the asymmetric unit. The structural features (bond lengths and angles) of the two mol-ecules are almost identical. The inter-planar angle between the anthracene and toluidine rings is similar in the two mol-ecules, with values of 82.92 (5) and 80.70 (5)°. In the crystal, both molecules form inversion dimers linked by pairs of N-H⋯O hydrogen bonds. Three of the four ethyl groups are disordered over two sets of sites, the major components having occupancies of 0.748 (15), 0.77 (4) and 0.518 (19).

| S-EPMC3213438 | biostudies-literature

Cyclo-hexyl-ammonium 4-meth-oxy-benzoate.

Project description:In the crystal of the title molecular salt, C(6)H(14)N(+)·C(8)H(7)O(3) (-), strong N-H?O hydrogen bonds are formed between the ammonium H atoms and the carboxyl-ate O atoms. The resulting supra-molecular structure is based on chains running in the [010] direction. The dihedral angle between the -CO(2) group and the benzene ring is 8.94?(17)° and the methoxy C atom deviates by 1.374?Å from the ring.

| S-EPMC3213617 | biostudies-literature

Ammonium diphenyl-phosphinate monohydrate.

Project description:In the title salt, NH(4) (+)·C(12)H(10)O(2)P(-)·H(2)O, the ion pair and water mol-ecule inter-act through hydrogen bonds to form a layer structure.

| S-EPMC2961549 | biostudies-literature

Diethyl [hydr-oxy(phen-yl)meth-yl]phospho-nate.

Project description:Mol-ecules of the title compound, C(11)H(17)O(4)P, are linked into chiral helical chains along the crystallographic b axis via O-H?O hydrogen bonds between the hydr-oxy group and an O atom of the phospho-nate group. One ethyl group is disordered over two positions; the site occupancy factors are ca 0.7 and 0.3.

| S-EPMC2961637 | biostudies-literature

(Z)-N-tert-Butyl-2-(4-meth-oxy-anilino)-N'-(4-meth-oxy-phen-yl)-2-phenyl-acetimidamide.

Project description:In the crystal of the title compound, C26H31N3O2, pairs of N-H?O hydrogen bonds link molecules, forming inversion dimers, which enclose an R 2 (2)(20) ring motif. One N atom does not form hydrogen bonds and lies in a hydro-phobic pocket with closest inter-molecular contacts of 4.196?(2) and 4.262?(2)?Å.

| S-EPMC3685058 | biostudies-literature

Bis(4-meth-oxy-benzyl-ammonium) dihydrogen diphosphate.

Project description:In the title compound, 2C(8)H(12)NO(+)·H(2)P(2)O(7) (2-), the linked PO(4) groups of the diphosphate anion are almost eclipsed and the P-O-P angle is 134.45?(7)°. In the crystal, infinite ribbons of H(2)P(2)O(7) (2-) anions propagate in [100], being linked by strong O-H?O hydrogen bonds. The 4-meth-oxy-benzyl-ammonium cations bond to the diphosphate chains by N-H?O and C-H?O links, and are themselves linked by C-H?? inter-actions.

| S-EPMC3569749 | biostudies-literature

rac-{[2-(Diphenyl-thio-phosphor-yl)ferrocen-yl]meth-yl}dimethyl-ammonium diphenyl-dithio-phosphinate.

Project description:2-(Diphenyl-thio-phosphino)dimethyl-amino-methyl-ferrocene is a key inter-mediate in the synthesis of various ferrocenyl ligands. During one such synthesis, the title compound, [Fe(C(5)H(5))(C(20)H(22)NPS)](C(12)H(10)PS(2)), was isolated as a by-product. It is built up by association of (2-(diphenyl-phosphino)ferrocen-yl)meth-yl)dimethyl-ammonium cations and diphenyl-phosphino dithio-ate anions. N-H?S, C-H?S and C-H?? inter-actions link the anions and cations. Each anion-cation pair is linked two by two through C-H?? inter-actions, forming pseudo dimers.

| S-EPMC3343798 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data