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Bis(4-meth-oxy-benzyl-ammonium) dihydrogen diphosphate.

ABSTRACT: In the title compound, 2C(8)H(12)NO(+)·H(2)P(2)O(7) (2-), the linked PO(4) groups of the diphosphate anion are almost eclipsed and the P-O-P angle is 134.45?(7)°. In the crystal, infinite ribbons of H(2)P(2)O(7) (2-) anions propagate in [100], being linked by strong O-H?O hydrogen bonds. The 4-meth-oxy-benzyl-ammonium cations bond to the diphosphate chains by N-H?O and C-H?O links, and are themselves linked by C-H?? inter-actions.

SUBMITTER: Elboulali A

PROVIDER: S-EPMC3569749 | biostudies-literature | 2013 Feb

REPOSITORIES: biostudies-literature

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Bis(4-meth-oxy-benzyl-ammonium) dihydrogen diphosphate.

Elboulali Adel A Akriche Samah S Al-Deyab Salem S SS Rzaigui Mohamed M

Acta crystallographica. Section E, Structure reports online 20130109 Pt 2

In the title compound, 2C(8)H(12)NO(+)·H(2)P(2)O(7) (2-), the linked PO(4) groups of the diphosphate anion are almost eclipsed and the P-O-P angle is 134.45 (7)°. In the crystal, infinite ribbons of H(2)P(2)O(7) (2-) anions propagate in [100], being linked by strong O-H⋯O hydrogen bonds. The 4-meth-oxy-benzyl-ammonium cations bond to the diphosphate chains by N-H⋯O and C-H⋯O links, and are themselves linked by C-H⋯π inter-actions. ...[more]

PMID: 23424495

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