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Trans-Dichloridobis(2,2-dimethyl-prop-ane-1,3-diamine-?N,N')chromium(III) perchlorate.

ABSTRACT: In the title salt, [CrCl(2)(C(5)H(14)N(2))(2)]ClO(4), the Cr atom is in a trans-CrCl(2)N(4) octa-hedral environment comprising the four N atoms of two chelating 2,2-dimethyl-propane-1,3-diamine ligands and two Cl atoms. The two six-membered CrC(3)N(2) rings in the cation adopt anti chair-chair conformations with respect to each other. The perchlorate anion is disordered over two positions in respect of the Cl and an O atom in a 6:4 ratio. N-H?O hydrogen bonds link the cations and anions into a layer structure.

SUBMITTER: Choi JH

PROVIDER: S-EPMC2959603 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

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trans-Dichloridobis(2,2-dimethyl-prop-ane-1,3-diamine-κN,N')chromium(III) perchlorate.

Choi Jong-Ha JH Lee Sang Hak SH Lee Uk U

Acta crystallographica. Section E, Structure reports online 20081018 Pt 11

In the title salt, [CrCl(2)(C(5)H(14)N(2))(2)]ClO(4), the Cr atom is in a trans-CrCl(2)N(4) octa-hedral environment comprising the four N atoms of two chelating 2,2-dimethyl-propane-1,3-diamine ligands and two Cl atoms. The two six-membered CrC(3)N(2) rings in the cation adopt anti chair-chair conformations with respect to each other. The perchlorate anion is disordered over two positions in respect of the Cl and an O atom in a 6:4 ratio. N-H⋯O hydrogen bonds link the cations and anions into a l ...[more]

PMID: 21580872

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