Unknown

Dataset Information

0

Tetra-kis[tris-(2,2'-bi-1H-benzimidazole)nickel(II)] bis-(phosphate) sulfate.

ABSTRACT: The title compound, [Ni(C(14)H(10)N(4))(3)](4)(PO(4))(2)(SO(4)), consists of [Ni(C(14)H(10)N(4))(3)](2+) complex cations (.3. symmetry) and disordered anions ( symmetry) with occupancy factors of two-thirds for PO(4) (3-) and one-third for SO(4) (2-). The Ni(2+) centre is chelated by three bidentate 2,2'-bi-1H-benzimidazole mol-ecules in a distorted octa-hedral coordination. N-H?O hydrogen bonds consolidate the building units into a framework structure.

SUBMITTER: Ling CS 

PROVIDER: S-EPMC2959627 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Tetra-kis[tris-(2,2'-bi-1H-benzimidazole)nickel(II)] bis-(phosphate) sulfate.

Ling Chun-Sheng CS   Yan Lin L  

Acta crystallographica. Section E, Structure reports online 20081015 Pt 11

The title compound, [Ni(C(14)H(10)N(4))(3)](4)(PO(4))(2)(SO(4)), consists of [Ni(C(14)H(10)N(4))(3)](2+) complex cations (.3. symmetry) and disordered anions ( symmetry) with occupancy factors of two-thirds for PO(4) (3-) and one-third for SO(4) (2-). The Ni(2+) centre is chelated by three bidentate 2,2'-bi-1H-benzimidazole mol-ecules in a distorted octa-hedral coordination. N-H⋯O hydrogen bonds consolidate the building units into a framework structure. ...[more]

Similar Datasets

Unknown Tris(2,2'-bi-1H-imidazole-?N,N)cobalt(II) hydrogen phosphate.
| S-EPMC3201263 | biostudies-literature
Unknown Tris(2,2'-bi-1H-imidazole-?N,N)-nickel(II) dinitrate N,N-dimethyl-formamide monosolvate.
| S-EPMC3247001 | biostudies-literature
Unknown Dimethyl 2,2'-[2,2'-bi(1H-1,3-benzimidazole)-1,1'-di-yl]diacetate.
| S-EPMC3414963 | biostudies-literature
Unknown Tetra-kis(1H-benzimidazole-?N)(nitrato-?O)copper(II) nitrate.
| S-EPMC3120510 | biostudies-literature
Unknown Tetra-kis(1-benzyl-1H-imidazole)dichlorido-nickel(II).
| S-EPMC2977609 | biostudies-literature
Unknown Tetra-aqua-(2,2'-bipyridine-?²N,N')nickel(II) sulfate.
| S-EPMC3393179 | biostudies-literature
Unknown trans-Diacetonitrile-tetra-kis(1H-pyrazole-?N)nickel(II) dinitrate.
| S-EPMC2971772 | biostudies-literature
Unknown cyclo-Tetra-kis{?-2,2'-dimethyl-1,1'-[2,2-bis-(bromo-meth-yl)propane-1,3-di-yl]di(1H-benzimidazole)-?N:N}tetra-kis-[bromidocopper(I)].
| S-EPMC3274886 | biostudies-other
Unknown Tetra-kis(1H-imidazole-?N)(2-phenyl-propanedioato-?O,O)nickel(II).
| S-EPMC3009345 | biostudies-literature
Unknown Crystal structure and Hirshfeld surface analysis of tris-(2,2'-bi-pyridine)-nickel(II) bis-(1,1,3,3-tetra-cyano-2-eth-oxy-propenide) dihydrate.
| S-EPMC6658966 | biostudies-literature