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8-Iodo-quinolinium triiodide tetra-hydro-furan solvate.

ABSTRACT: The title compound, C(9)H(7)IN(+)·I(3) (-)·C(4)H(8)O, was synthesized from 8-amino-quinoline using the Sandmeyer reaction. The 8-iodo-quinolinium cation is essentially planar and the triiodide ion is almost linear. N-H?O hydrogen bonds, and inter-molecular I?I [3.7100?(5)?Å] and I?H inter-actions, between the cation, anion and solvent mol-ecules result in the formation of sheets oriented parallel to the (03) plane. Between the sheets, 8-iodo-quinolinium and triiodide ions are stacked alternately, with I?C distances in the range ?3.8-4.0?Å.

SUBMITTER: Son JH

PROVIDER: S-EPMC2959684 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

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8-Iodo-quinolinium triiodide tetra-hydro-furan solvate.

Son Jung-Ho JH Hoefelmeyer James D JD

Acta crystallographica. Section E, Structure reports online 20081004 Pt 11

The title compound, C(9)H(7)IN(+)·I(3) (-)·C(4)H(8)O, was synthesized from 8-amino-quinoline using the Sandmeyer reaction. The 8-iodo-quinolinium cation is essentially planar and the triiodide ion is almost linear. N-H⋯O hydrogen bonds, and inter-molecular I⋯I [3.7100 (5) Å] and I⋯H inter-actions, between the cation, anion and solvent mol-ecules result in the formation of sheets oriented parallel to the (03) plane. Between the sheets, 8-iodo-quinolinium and triiodide ions are stacked alternately ...[more]

PMID: 21580942

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