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Chloridonitros-yl[meso-5,10,15,20-tetra-kis-(p-tol-yl)porphyrinato-?N,N',N'',N''']osmium(II) tetra-hydro-furan tetra-solvate.

ABSTRACT: The title compound, [OsCl(NO)(C(48)H(36)N(4))]·4C(4)H(8)O, is a six-coordinate osmium(II) porphyrin complex with nitrosyl (NO) and chloride (Cl) ligands trans to each other in an octa-hedral geometry. The metal complex lies on a fourfold rotation axis that passes through the Os, N, O and Cl atoms. The NO and Cl ligands are disordered in an 0.511?(12):0.486?(12) ratio.

SUBMITTER: Chen L

PROVIDER: S-EPMC3051540 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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Chloridonitros-yl[meso-5,10,15,20-tetra-kis-(p-tol-yl)porphyrinato-κN,N',N'',N''']osmium(II) tetra-hydro-furan tetra-solvate.

Chen Li L Xu Nan N Powell Douglas R DR Richter-Addo George B GB

Acta crystallographica. Section E, Structure reports online 20110122 Pt 2

The title compound, [OsCl(NO)(C(48)H(36)N(4))]·4C(4)H(8)O, is a six-coordinate osmium(II) porphyrin complex with nitrosyl (NO) and chloride (Cl) ligands trans to each other in an octa-hedral geometry. The metal complex lies on a fourfold rotation axis that passes through the Os, N, O and Cl atoms. The NO and Cl ligands are disordered in an 0.511 (12):0.486 (12) ratio. ...[more]

PMID: 21522883

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