Browse
Submit Data
Databases
API
Help

Dataset Information

24 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

3,4-Dimeth-oxy-N-(4-nitro-benzyl-idene)-aniline.

ABSTRACT: In the title mol-ecule, C(15)H(14)N(2)O(4), the dihedral angle between the two benzene rings is 29.52?(8)°. The nitro and two meth-oxy substituents are almost coplanar with their respective benzene rings. The crystal structure is stabilized by inter-molecular C-H?O inter-actions.

SUBMITTER: Akkurt M

PROVIDER: S-EPMC2959688 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

3,4-Dimeth-oxy-N-(4-nitro-benzyl-idene)-aniline.

Akkurt Mehmet M Jarrahpour Aliasghar A Aye Malihe M Gençaslan Mustafa M Büyükgüngör Orhan O

Acta crystallographica. Section E, Structure reports online 20081009 Pt 11

In the title mol-ecule, C(15)H(14)N(2)O(4), the dihedral angle between the two benzene rings is 29.52 (8)°. The nitro and two meth-oxy substituents are almost coplanar with their respective benzene rings. The crystal structure is stabilized by inter-molecular C-H⋯O inter-actions. ...[more]

PMID: 21580952

Similar Datasets

3,4-Dimeth-oxy-N-(3-nitro-benzyl-idene)aniline.

Project description:The title compound, C(15)H(14)N(2)O(4), has two crystallographically independent mol-ecules in the asymmetric unit. In both mol-ecules, the nitro and the two meth-oxy substituents are coplanar with the benzene rings to which they are attached. The benzene rings are nearly coplanar, with dihedral angles between the two benzene rings of 10.39?(8) and 5.95?(8)° in the two mol-ecules. The two independent mol-ecules in the asymmetric unit are rotated with respect to each other such that the dihedral angles between equivalent benzene rings are 49.11?(8) and 63.93?(8)°. In the crystal structure, inter-molecular C-H?O hydrogen-bond contacts and a weak C-H?? inter-action are observed.

| S-EPMC2959659 | biostudies-literature

N-[(E)-3,4-Dimeth-oxy-benzyl-idene]-2,3-dimethyl-aniline.

Project description:In the title compound, C(17)H(19)NO(2), the aromatic rings are oriented at a dihedral angle of 59.27?(12)°. In the crystal, inversion dimers linked by pairs of weak C-H?O inter-actions generate R(2) (2)(12) loops.

| S-EPMC3200881 | biostudies-other

N'-(3,4-Dimeth-oxy-benzyl-idene)benzo-hydrazide.

Project description:The crystal structure of the title Schiff base compound, C(16)H(16)N(2)O(3), is characterized by chains of mol-ecules linked by inter-molecular N-H?O hydrogen bonds running along the c axis. Further stabilization is provided by weak C-H?O contacts. The dihedral angle between the aromatic rings is 38.31?(7)°.

| S-EPMC3050232 | biostudies-literature

2-[(E)-3,4-Dimeth-oxy-benzyl-idene]hydrazinecarboxamide.

Project description:In the title compound, C(10)H(13)N(3)O(3), the 3,4-dimeth-oxy-benzyl-idene and hydrazinecarboxamide groups are oriented at a dihedral angle of 53.82?(6)° and an intra-molecular N-H?N hydrogen bond generates an S(5) ring motif. In the crystal, mol-ecules are linked by N-H?O hydrogen bonds into sheets propagating in (-201), which feature R(1) (2)(5), R(2) (2)(8) and R(2) (4)(14) loops.

| S-EPMC3379314 | biostudies-literature

(E)-N-(2,4-Dichloro-benzyl-idene)-2,5-dimeth-oxy-aniline.

Project description:In the title compound, C15H13Cl2NO2, which was obtained by a condensation reaction of 2,5-dimeth-oxy-aniline and 2,4-dichloro-benzaldehyde, the dihedral angle between the benzene rings is 51.94?(2)°. The 2,5-dimeth-oxy-phenyl and 2,4-dichloro-phenyl groups are attached to the ends of the N=C group in an E conformation. Intra-molecular C-H?Cl and C-H?N contacts are observed. In the crystal, mol-ecules are linked by C-H?O hydrogen bonds, forming chains parallel to the b axis.

| S-EPMC3629509 | biostudies-literature

4-Meth-oxy-N-(2-nitro-benzyl-idene)aniline.

Project description:The title compound, C(14)H(12)N(2)O(3), was prepared by reaction of 2-nitro-benzaldehyde with 4-methoxy-benzenamine at 377?K. The molecule has an E configuration, with a dihedral angle between the two benzene rings of 43.3?(5)°. An intermolecular C-H?O interaction links molecules in zigzag chains down the a axis.

| S-EPMC2959339 | biostudies-literature

4-Chloro-N-[(E)-(3,4-dimeth-oxy-phen-yl)methyl-idene]aniline.

Project description:The asymmetric unit of the title compound, C(15)H(14)ClNO(2), contains two mol-ecules with significantly different conformations: the dihedral angles between the 4-chloro-aniline and 3,4-dimeth-oxy-phenyl (excluding C atoms) moieties are 19.68?(7) and 45.54?(4)°. In the crystal, the mol-ecules are linked by C-H?O hydrogen bonds and weak C-H?? inter-actions.

| S-EPMC3008132 | biostudies-literature

(E)-2-(3,4-Dimeth-oxy-benzyl-idene)-5,6-dimeth-oxy-2,3-dihydro-1H-inden-1-one.

Project description:In the title compound, C(20)H(20)O(5), the 2,3-dihydro-1H-indene ring system is essentially planar [maximum deviation = 0.010?(1)?Å] and is inclined at an angle of 4.09?(4)° with respect to the phenyl ring. The C=C bond has an E configuration. In the crystal, the mol-ecules are linked into chains propagating in [102] via inter-molecular C-H?O hydrogen bonds. The crystal structure is further consolidated by C-H?? inter-actions.

| S-EPMC3009320 | biostudies-literature

3,4-Dimeth-oxy-N-((E)-4-{[1-(prop-2-en-1-yl)-1H-1,2,3-triazol-4-yl]meth-oxy}benzyl-idene)aniline.

Project description:In the title compound, C(21)H(22)N(4)O(3), the triazole ring is planar [maximum deviaton = 0.004 (1) Å] and makes dihedral angles of 26.21 (8) and 38.66 (8)° with the two benzene rings. In the crystal, mol-ecules are linked by C-H⋯O hydrogen bonds, forming zigzag chains along [1-11]. In addition, a weak C-H⋯π intreraction is also observed.

| S-EPMC3393938 | biostudies-literature

5-(3,4-Dimeth-oxy-benzyl-idene)-1,3-dimethyl-1,3-diazinane-2,4,6-trione.

Project description:In the title compound, C(15)H(16)N(2)O(5), the dihedral angle between 1,3-diazinane and benzene rings is only 4.27?(1)°. The essentially planar mol-ecular structure is characterized by a short intra-molecular C-H?O separation and by an exceptionally large bond angle of 138.25?(14)° at the bridging methine C atom. The meth-oxy groups deviate somewhat from the plane of the benzene ring, with C-C-O-C torsion angles of -15.6?(1) and 9.17?(6)°. In the crystal, mol-ecules form centrosymmetric dimers via donor-acceptor ?-? inter-actions, with a centroid-centroid distance of 3.401?(1)?Å.

| S-EPMC3254518 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data