Browse
Submit Data
Databases
API
Help

Dataset Information

32 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

4-Meth-oxy-N-(2-nitro-benzyl-idene)aniline.

ABSTRACT: The title compound, C(14)H(12)N(2)O(3), was prepared by reaction of 2-nitro-benzaldehyde with 4-methoxy-benzenamine at 377?K. The molecule has an E configuration, with a dihedral angle between the two benzene rings of 43.3?(5)°. An intermolecular C-H?O interaction links molecules in zigzag chains down the a axis.

SUBMITTER: Ren XY

PROVIDER: S-EPMC2959339 | biostudies-literature | 2008 Sep

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

4-Meth-oxy-N-(2-nitro-benzyl-idene)aniline.

Ren Xiao-Yan XY Jian Fang-Fang FF

Acta crystallographica. Section E, Structure reports online 20080927 Pt 10

The title compound, C(14)H(12)N(2)O(3), was prepared by reaction of 2-nitro-benzaldehyde with 4-methoxy-benzenamine at 377 K. The molecule has an E configuration, with a dihedral angle between the two benzene rings of 43.3 (5)°. An intermolecular C-H⋯O interaction links molecules in zigzag chains down the a axis. ...[more]

PMID: 21201221

Similar Datasets

3,4-Dimeth-oxy-N-(4-nitro-benzyl-idene)-aniline.

Project description:In the title mol-ecule, C(15)H(14)N(2)O(4), the dihedral angle between the two benzene rings is 29.52 (8)°. The nitro and two meth-oxy substituents are almost coplanar with their respective benzene rings. The crystal structure is stabilized by inter-molecular C-H⋯O inter-actions.

| S-EPMC2959688 | biostudies-literature

3,4-Dimeth-oxy-N-(3-nitro-benzyl-idene)aniline.

Project description:The title compound, C(15)H(14)N(2)O(4), has two crystallographically independent mol-ecules in the asymmetric unit. In both mol-ecules, the nitro and the two meth-oxy substituents are coplanar with the benzene rings to which they are attached. The benzene rings are nearly coplanar, with dihedral angles between the two benzene rings of 10.39 (8) and 5.95 (8)° in the two mol-ecules. The two independent mol-ecules in the asymmetric unit are rotated with respect to each other such that the dihedral angles between equivalent benzene rings are 49.11 (8) and 63.93 (8)°. In the crystal structure, inter-molecular C-H⋯O hydrogen-bond contacts and a weak C-H⋯π inter-action are observed.

| S-EPMC2959659 | biostudies-literature

4-Meth-oxy-N'-(3-nitro-benzyl-idene)benzohydrazide.

Project description:In the title compound, C(15)H(13)N(3)O(4), the dihedral angle between the benzene rings is 3.1?(3)°. The mol-ecule displays an E conformation about the C=N bond. In the crystal, mol-ecules are linked via N-H?O hydrogen bonds, generating chains that propagate along the b-axis direction. There is also a C-H?O inter-action present.

| S-EPMC3379315 | biostudies-literature

N'-(2-Meth-oxy-benzyl-idene)-4-nitro-benzohydrazide.

Project description:The mol-ecule of the title compound, C(15)H(13)N(3)O(4), adopts an E configuration with respect to the C=N bond. The dihedral angle between the two benzene rings is 6.0 (3)°. In the crystal, mol-ecules are linked through inter-molecular N-H⋯O hydrogen bonds to form chains along the c axis.

| S-EPMC3099914 | biostudies-literature

4-Fluoro-N-[(E)-3,4,5-tri-meth-oxy-benzyl-idene]aniline.

Project description:The title compound, C16H16FNO3, exists in a trans configuration with respect to the C=N bond [1.258?(2)?Å]. The central meth-oxy O atom deviates from the plane of the attached benzene ring by 0.0911?(14)?Å. The dihedral angle between the aromatic rings is 47.58?(11)°. The crystal structure features C-H?N and C-H?O inter-actions.

| S-EPMC3793738 | biostudies-literature

(E)-N'-(2-Meth-oxy-benzyl-idene)-3-nitro-benzohydrazide.

Project description:In the title compound, C(15)H(13)N(3)O(4), the two substituted benzene rings form a dihedral angle of 10.9?(3)°. In the crystal, inter-molecular C-H?O and N-H?O hydrogen bonds link mol-ecules into chains running parallel to [101].

| S-EPMC3212289 | biostudies-literature

(E)-2-Meth-oxy-N'-(4-nitro-benzyl-idene)benzohydrazide.

Project description:In the title compound, C(15)H(13)N(3)O(4), the mol-ecule exists in a trans configuration with respect to the methyl-idene unit. The dihedral angle between the two benzene rings is 6.8?(2)°. The C-N-NH-C torsion angle is 3.4?(3)°. The mol-ecule possesses an intra-molecular N-H?O hydrogen bond. In the crystal structure, adjacent mol-ecules are linked through inter-molecular C-H?O hydrogen bonds, forming dimers.

| S-EPMC2972042 | biostudies-literature

N-(3-Nitro-benzyl-idene)aniline.

Project description:In the title compound, C(13)H(10)N(2)O(2), a Schiff base derivative, the dihedral angle between the two aromatic rings is 31.58 (3)°. The C=N double bond is essentially coplanar with the nitro-phenyl ring. The torsion angle of the imine double bond is 175.97 (13)°, indicating that the C=N double bond is in a trans configuration. The crystal structure is stabilized by C-H⋯O contacts and π-π inter-actions (centroid-centroid distances of 3.807 and 3.808Å).

| S-EPMC2960009 | biostudies-literature

N'-(2-Hy-droxy-4-meth-oxy-benzyl-idene)-3-nitro-benzohydrazide.

Project description:In the mol-ecule of the title compound, C(15)H(13)N(3)O(3), an intra-molecular O-H?N hydrogen bond influences the planarity of the conformation; the dihedral angle between the benzene rings is 11.4?(3)°. In the crystal, mol-ecules are linked by N-H?O hydrogen bonds into chains in [101].

| S-EPMC3247367 | biostudies-literature

(E)-4-Meth-oxy-N'-(4-nitro-benzyl-idene)benzohydrazide methanol monosolvate.

Project description:The hydrazone mol-ecule of the title compound, C(15)H(13)N(3)O(4)·CH(4)O, is nearly planar, with a dihedral angle between the two benzene rings of 1.2?(4)°. The mol-ecule exists in a trans configuration with respect to the central methyl-idene unit. In the crystal, the benzohydrazide and methanol mol-ecules are linked through inter-molecular O-H?O, O-H?N and N-H?O hydrogen bonds, forming chains along the a axis.

| S-EPMC3011623 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data