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1-(4-Bromo-phen-yl)ferrocene.

ABSTRACT: In the title compound, [Fe(C(5)H(5))(C(11)H(8)Br)], the distance of the Fe atom from the centroids of the unsubstituted and substituted cyclo-penta-dienyl (Cp) rings is 1.644?(1) and 1.643?(1)?Å, respectively. The ferrocenyl moiety deviates from an eclipsed geometry, with marginally tilted Cp rings and an inter-planar angle between the Cp and benzene rings of 13.0?(4)°. The crystal structure is stabilized by C-H?? inter-actions between a cyclo-penta-dienyl H atom and the cyclo-penta-dienyl ring of a neighbouring mol-ecule.

SUBMITTER: Nyamori VO

PROVIDER: S-EPMC2959700 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

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1-(4-Bromo-phen-yl)ferrocene.

Nyamori Vincent O VO Bala Muhammad D MD

Acta crystallographica. Section E, Structure reports online 20081009 Pt 11

In the title compound, [Fe(C(5)H(5))(C(11)H(8)Br)], the distance of the Fe atom from the centroids of the unsubstituted and substituted cyclo-penta-dienyl (Cp) rings is 1.644 (1) and 1.643 (1) Å, respectively. The ferrocenyl moiety deviates from an eclipsed geometry, with marginally tilted Cp rings and an inter-planar angle between the Cp and benzene rings of 13.0 (4)°. The crystal structure is stabilized by C-H⋯π inter-actions between a cyclo-penta-dienyl H atom and the cyclo-penta-dienyl ring ...[more]

PMID: 21580832

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