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(4-{[(Pyridin-4-yl)methyl-idene]amino}-phen-yl)ferrocene.

ABSTRACT: The asymetric unit of the title compound, [Fe(C5H5)(C17H13N2)], contains two independent mol-ecules whose conformations differ, especially in the 4-{(pyridin-4-yl)methyl-idene]amino}-phenyl unit where one is flipped by almost 180°. The cyclo-penta-dienyl rings of the ferrocene unit also exhibit different staggered conformations: in one mol-ecule the conformation is staggered by 9.43?(2)° and in the other by 24.46?(1)° from an ideal eclipsed geometry. The plane of the benzene ring is tilted away from the ferrocene group in both mol-ecules, with dihedral angles of 6.97?(1) and 10.30?(2)°. The benzene ring is also slightly twisted from the plane of the pyridine ring, with dihedral angles of 5.98?(2) and 6.51?(2)° in the two mol-ecules.

SUBMITTER: Nyamori VO 

PROVIDER: S-EPMC3588778 | biostudies-literature | 2012 Dec

REPOSITORIES: biostudies-literature

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(4-{[(Pyridin-4-yl)methyl-idene]amino}-phen-yl)ferrocene.

Nyamori Vincent O VO   Keru Godfrey G   Omondi Bernard B  

Acta crystallographica. Section E, Structure reports online 20121124 Pt 12

The asymetric unit of the title compound, [Fe(C5H5)(C17H13N2)], contains two independent mol-ecules whose conformations differ, especially in the 4-{(pyridin-4-yl)methyl-idene]amino}-phenyl unit where one is flipped by almost 180°. The cyclo-penta-dienyl rings of the ferrocene unit also exhibit different staggered conformations: in one mol-ecule the conformation is staggered by 9.43 (2)° and in the other by 24.46 (1)° from an ideal eclipsed geometry. The plane of the benzene ring is tilted away  ...[more]

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