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Triphen-yl(tetra-hydro-furan)-aluminium(III).

ABSTRACT: In the title compound, [Al(C(6)H(5))(3)(C(4)H(8)O)], the Al atom has a distorted tetra-hedral geometry. The C-Al-C angles range from 113.25?(7) to 116.27?(8)°, much larger than the O-Al-C angles, which range from 103.39?(7) to 103.90?(6)°. The tetra-hydro-furan ring adopts an envelope conformation. The crystal packing is stabilized by C-H?? inter-actions.

SUBMITTER: Chen CR

PROVIDER: S-EPMC2959725 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

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Triphen-yl(tetra-hydro-furan)-aluminium(III).

Chen Chi-Ren CR Gau Han-Mou HM

Acta crystallographica. Section E, Structure reports online 20081011 Pt 11

In the title compound, [Al(C(6)H(5))(3)(C(4)H(8)O)], the Al atom has a distorted tetra-hedral geometry. The C-Al-C angles range from 113.25 (7) to 116.27 (8)°, much larger than the O-Al-C angles, which range from 103.39 (7) to 103.90 (6)°. The tetra-hydro-furan ring adopts an envelope conformation. The crystal packing is stabilized by C-H⋯π inter-actions. ...[more]

PMID: 21580835

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