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{2-[Bis(3-methyl-1H-indol-2-yl)meth-yl]phenolato-?O}dimeth-yl(tetra-hydro-furan-?O)aluminium(III).

ABSTRACT: The title compound, [Al(CH(3))(2)(C(25)H(21)N(2)O)(C(4)H(8)O)], was isolated as a minor component from a reaction mixture of the parent indolyl ligand and trimethyl-aluminum in tetra-hydro-furan. The ligands adopt a distorted tetra-hedral geometry around aluminium. Obvious hydrogen-bonding interactions are not present.

SUBMITTER: Eisenberg AC

PROVIDER: S-EPMC2971370 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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{2-[Bis(3-methyl-1H-indol-2-yl)meth-yl]phenolato-κO}dimeth-yl(tetra-hydro-furan-κO)aluminium(III).

Eisenberg Audrey C AC Tanski Joseph M JM Getzler Yutan D Y L YD

Acta crystallographica. Section E, Structure reports online 20091013 Pt 11

The title compound, [Al(CH(3))(2)(C(25)H(21)N(2)O)(C(4)H(8)O)], was isolated as a minor component from a reaction mixture of the parent indolyl ligand and trimethyl-aluminum in tetra-hydro-furan. The ligands adopt a distorted tetra-hedral geometry around aluminium. Obvious hydrogen-bonding interactions are not present. ...[more]

PMID: 21578108

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