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2,4-Bis[bis(diisopropyl-amino)-phos-phanyl]-1,2,3,4-tetra-phospha-bicyclo[1.1.0]butane.

ABSTRACT: The title compound, C(24)H(56)N(4)P(6) or ((i)Pr(2)N)(2)P-P(4)-P(N(i)Pr(2))(2), adopts a butterfly structure, with planar environments for the N atoms and pyramidal environments for the P atoms. The structure studied has a 15% twin component that is related by a twofold rotation about [100].

SUBMITTER: Lapczuk-Krygier A

PROVIDER: S-EPMC2959955 | biostudies-literature | 2008 Nov

REPOSITORIES: biostudies-literature

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2,4-Bis[bis(diisopropyl-amino)-phos-phanyl]-1,2,3,4-tetra-phospha-bicyclo[1.1.0]butane.

Lapczuk-Krygier Agnieszka A Baranowska Katarzyna K Pikies Jerzy J

Acta crystallographica. Section E, Structure reports online 20081122 Pt 12

The title compound, C(24)H(56)N(4)P(6) or ((i)Pr(2)N)(2)P-P(4)-P(N(i)Pr(2))(2), adopts a butterfly structure, with planar environments for the N atoms and pyramidal environments for the P atoms. The structure studied has a 15% twin component that is related by a twofold rotation about [100]. ...[more]

PMID: 21581395

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