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2,4-Bis(diphenyl-phosphan-yl)-1,1,2,3,3,4-hexa-phenyl-1,3-diphospha-2,4-dibora-cyclo-butane tetra-hydro-furan sesqui-solvate.

ABSTRACT: In the title compound, C(60)H(50)B(2)P(4)·1.5C(4)H(8)O, the diphospha-diborane mol-ecule lies on an inversion centre, whereas the disordered tetra-hydro-furan solvent mol-ecule is in a general position with a partial occupancy of 0.75. The diphosphadiborane mol-ecule consists of an ideal planar four-membered B(2)P(2) ring with an additional phenyl and a -PPh(2) group attached to each B atom.

SUBMITTER: Peulecke N

PROVIDER: S-EPMC3344071 | biostudies-literature | 2012 Apr

REPOSITORIES: biostudies-literature

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2,4-Bis(diphenyl-phosphan-yl)-1,1,2,3,3,4-hexa-phenyl-1,3-diphospha-2,4-dibora-cyclo-butane tetra-hydro-furan sesqui-solvate.

Peulecke Normen N Müller Bernd H BH Spannenberg Anke A Rosenthal Uwe U

Acta crystallographica. Section E, Structure reports online 20120321 Pt 4

In the title compound, C(60)H(50)B(2)P(4)·1.5C(4)H(8)O, the diphospha-diborane mol-ecule lies on an inversion centre, whereas the disordered tetra-hydro-furan solvent mol-ecule is in a general position with a partial occupancy of 0.75. The diphosphadiborane mol-ecule consists of an ideal planar four-membered B(2)P(2) ring with an additional phenyl and a -PPh(2) group attached to each B atom. ...[more]

PMID: 22589980

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