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Bis(μ-5-diisopropyl-amino-1,2,3,4-tetra-zolido-κN:N)bis-[(triisopropyl-phosphane)copper(I)].

ABSTRACT: In the binuclear centrosymmetric crystal structure of the title compound, [Cu(2)(C(7)H(14)N(5))(2)(C(9)H(21)P)(2)], all atoms except those of the isopropyl groups are approximately co-planar. The Cu(II) atom is in a distorted trigonal-planar CuN(2)P coordination. Bond angles around the amino N atom suggest sp(2) hybridization. Several intra-molecular C-H⋯N inter-actions are present involving tetra-zolate N atoms.

SUBMITTER: Kobrsi I

PROVIDER: S-EPMC3151938 | biostudies-literature | 2011 Jul

REPOSITORIES: biostudies-literature

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Bis(μ-5-diisopropyl-amino-1,2,3,4-tetra-zolido-κN:N)bis-[(triisopropyl-phosphane)copper(I)].

Kobrsi Issam I Bassioni Ghada G

Acta crystallographica. Section E, Structure reports online 20110625 Pt 7

In the binuclear centrosymmetric crystal structure of the title compound, [Cu(2)(C(7)H(14)N(5))(2)(C(9)H(21)P)(2)], all atoms except those of the isopropyl groups are approximately co-planar. The Cu(II) atom is in a distorted trigonal-planar CuN(2)P coordination. Bond angles around the amino N atom suggest sp(2) hybridization. Several intra-molecular C-H⋯N inter-actions are present involving tetra-zolate N atoms. ...[more]

PMID: 21836950

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