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Di-?-chlorido-bis-{bis-[3,5-dimethyl-pyrazol-1-yl-?N)methane]iron(II)} bis-[tetra-chloridoferrate(III)].

ABSTRACT: In the title complex, [Fe(2)Cl(2)(C(11)H(16)N(4))(4)][FeCl(4)](2), the asymmetric unit is composed of one and a half units of [Fe(bdmpm)(2)Cl](2)(FeCl(4))(2)(bdmpm = bis(bis(3,5-dimethyl-pyrazol-1-yl)methane). The three independent Fe(II) atom have a distorted octa-hedral coordination geometry comprising two bridging chloride anions and four N atoms from two bis-(3,5-dimethyl-pyrazol-1-yl)methane ligands. The Fe(III) atom has a tetra-hedral coordination geometry comprising four chloride anions.

SUBMITTER: Xia H

PROVIDER: S-EPMC2959963 | biostudies-literature | 2008

REPOSITORIES: biostudies-literature

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Di-μ-chlorido-bis-{bis-[3,5-dimethyl-pyrazol-1-yl-κN)methane]iron(II)} bis-[tetra-chloridoferrate(III)].

Xia Hongying H Liu Yuelong Y

Acta crystallographica. Section E, Structure reports online 20081108 Pt 12

In the title complex, [Fe(2)Cl(2)(C(11)H(16)N(4))(4)][FeCl(4)](2), the asymmetric unit is composed of one and a half units of [Fe(bdmpm)(2)Cl](2)(FeCl(4))(2)(bdmpm = bis(bis(3,5-dimethyl-pyrazol-1-yl)methane). The three independent Fe(II) atom have a distorted octa-hedral coordination geometry comprising two bridging chloride anions and four N atoms from two bis-(3,5-dimethyl-pyrazol-1-yl)methane ligands. The Fe(III) atom has a tetra-hedral coordination geometry comprising four chloride anions. ...[more]

PMID: 21581124

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