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Dicarbon-yl[2-hydr-oxy-3,5,7-tris-(mor-pho-linomethyl)cyclo-hepta-2,4,6-trien-onato(1-)-?O,O]rhodium(I).

ABSTRACT: In the title compound, [Rh(C(22)H(32)N(3)O(5))(CO)(2)], the Rh(I) atom is coordinated by two carbonyl ligands and two tropolonate O atoms in a distorted square-planar geometry. It is an example of a new type of tropolone derivative that has not been characterized via solid-state methods. Weak intra-molecular C-H?N and inter-molecular C-H?O hydrogen bonds, and ?-? stacking inter-actions between the tropolone rings [centroid-centroid distance = 3.590?(8)?Å] are observed in the crystal structure.

SUBMITTER: Hill TN

PROVIDER: S-EPMC2960118 | biostudies-literature | 2008 Nov

REPOSITORIES: biostudies-literature

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Dicarbon-yl[2-hydr-oxy-3,5,7-tris-(mor-pho-linomethyl)cyclo-hepta-2,4,6-trien-onato(1-)-κO,O]rhodium(I).

Hill Tania N TN Steyl G G

Acta crystallographica. Section E, Structure reports online 20081120 Pt 12

In the title compound, [Rh(C(22)H(32)N(3)O(5))(CO)(2)], the Rh(I) atom is coordinated by two carbonyl ligands and two tropolonate O atoms in a distorted square-planar geometry. It is an example of a new type of tropolone derivative that has not been characterized via solid-state methods. Weak intra-molecular C-H⋯N and inter-molecular C-H⋯O hydrogen bonds, and π-π stacking inter-actions between the tropolone rings [centroid-centroid distance = 3.590 (8) Å] are observed in the crystal structure. ...[more]

PMID: 21581182

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