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Dicarbon-yl[4-(2,6-dimethyl-phenyl-amino)-pent-3-en-2-onato-?(2)N,O]rhodium(I).

ABSTRACT: In the title compound, [Rh(C(13)H(16)NO)(CO)(2)], a square-planar coordination geometry is observed around the Rh(I) atom, formed by the N and O atoms of the bidentate ligand and two C atoms from two carbonyl ligands. The Rh(I) atom is displaced from the plane through these surrounding atoms by 0.0085?(2)?Å. The dihedral angle between the benzene ring and the N-C-C-C-O plane is 89.82?(6)°, and the N-Rh-O bite angle for the bidentate ligand is 90.53?(6)°. An inter-molecular C-H?O inter-action is observed between a methyl group of the benzene ring and a carbonyl O atom.

SUBMITTER: Venter GJ

PROVIDER: S-EPMC3344388 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

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Dicarbon-yl[4-(2,6-dimethyl-phenyl-amino)-pent-3-en-2-onato-κ(2)N,O]rhodium(I).

Venter Gertruida J S GJ Steyl Gideon G Roodt Andreas A

Acta crystallographica. Section E, Structure reports online 20120425 Pt 5

In the title compound, [Rh(C(13)H(16)NO)(CO)(2)], a square-planar coordination geometry is observed around the Rh(I) atom, formed by the N and O atoms of the bidentate ligand and two C atoms from two carbonyl ligands. The Rh(I) atom is displaced from the plane through these surrounding atoms by 0.0085 (2) Å. The dihedral angle between the benzene ring and the N-C-C-C-O plane is 89.82 (6)°, and the N-Rh-O bite angle for the bidentate ligand is 90.53 (6)°. An inter-molecular C-H⋯O inter-action is ...[more]

PMID: 22590150

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