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Bis(?-cyclo-hepta-trien-yl)tri-?-hydrido-dimolybdenum(0,I).

ABSTRACT: In the title compound, [Mo(2)(?(7)-C(7)H(7))(2)(?-H)(3)], which displays crystallographic mirror symmetry, two (?(7)-C(7)H(7))Mo units are linked along the Mo-Mo axis by three bridging hydride ligands. The Mo-Mo distance is 2.5732?(4)?Å. The perpendicular distances of the Mo atoms from the C(7) planes are 1.5827?(8) and 1.5814?(8)?Å, with individual Mo-C bond lengths in the range 2.261?(2)-2.2789?(14)?Å. Mo-H distances range from 1.77?(3) to 1.85?(4)?Å, with Mo-H-Mo angles of 89?(2) and 92?(1)°.

SUBMITTER: Jones PG

PROVIDER: S-EPMC2967928 | biostudies-literature | 2008 Dec

REPOSITORIES: biostudies-literature

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Bis(η-cyclo-hepta-trien-yl)tri-μ-hydrido-dimolybdenum(0,I).

Jones Peter G PG Hrib Cristian G CG Randoll Sören S Wu Xian X Tamm Matthias M

Acta crystallographica. Section E, Structure reports online 20081217 Pt 1

In the title compound, [Mo(2)(η(7)-C(7)H(7))(2)(μ-H)(3)], which displays crystallographic mirror symmetry, two (η(7)-C(7)H(7))Mo units are linked along the Mo-Mo axis by three bridging hydride ligands. The Mo-Mo distance is 2.5732 (4) Å. The perpendicular distances of the Mo atoms from the C(7) planes are 1.5827 (8) and 1.5814 (8) Å, with individual Mo-C bond lengths in the range 2.261 (2)-2.2789 (14) Å. Mo-H distances range from 1.77 (3) to 1.85 (4) Å, with Mo-H-Mo angles of 89 (2) and 92 (1)°. ...[more]

PMID: 21581559

Similar Datasets

Crystal structure of (18-crown-6)potassium(I) [(1,2,3,4,5-η)-cyclo-hepta-dien-yl][(1,2,3-η)-cyclo-hepta-trien-yl]cobalt(I).

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| S-EPMC4350718 | biostudies-literature

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| S-EPMC3344665 | biostudies-literature

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| S-EPMC2960118 | biostudies-literature

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