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Diacetatobis[1,3-bis-(benzimidazol-2-yl)benzene]zinc(II) dihydrate.

ABSTRACT: In the title complex, [Zn(CH(3)COO)(2)(C(20)H(14)N(4))(2)]·2H(2)O, the Zn(II) atom, which lies on a crystallographic twofold axis, is coordinated by two O atoms of two acetate ligands and two N atoms from two 1,3-bis-(benzimidazol-2-yl)benzene ligands in a distorted tetra-hedral geometry. The complex mol-ecules and solvent water mol-ecules are connected via O-H?N, O-H?O and N-H?O hydrogen bonds, forming a three-dimensional network.

SUBMITTER: Meng FY 

PROVIDER: S-EPMC2960180 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature

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Diacetatobis[1,3-bis-(benzimidazol-2-yl)benzene]zinc(II) dihydrate.

Meng Fa-Yan FY   Teng Lei L   Chen Xue Mei XM   Zhao Bi Lin BL   Jiao Ping P  

Acta crystallographica. Section E, Structure reports online 20080109 Pt 2

In the title complex, [Zn(CH(3)COO)(2)(C(20)H(14)N(4))(2)]·2H(2)O, the Zn(II) atom, which lies on a crystallographic twofold axis, is coordinated by two O atoms of two acetate ligands and two N atoms from two 1,3-bis-(benzimidazol-2-yl)benzene ligands in a distorted tetra-hedral geometry. The complex mol-ecules and solvent water mol-ecules are connected via O-H⋯N, O-H⋯O and N-H⋯O hydrogen bonds, forming a three-dimensional network. ...[more]

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