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(E)-N-[2-(9-Fluorenyl-idene)-3a,5,7-tri-methyl-3,3a-dihydro-2H-indol-3-yl-idene]-2,4,6-trimethyl-aniline.

ABSTRACT: The title compound, C(33)H(30)N(2), has an E configuration at the imine double bond. The angle between the least-squares planes of the imine C=N-C group and the benzene ring of the 2,4,6-trimethylphenyl substituent is 85.38?(11)°. The crystal structure is sustained mainly by inter-molecular ?-? inter-actions (3.510?Å) between the two fluorene rings and some C-H?? inter-actions.

SUBMITTER: Mizuhata Y

PROVIDER: S-EPMC2960190 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature

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(E)-N-[2-(9-Fluorenyl-idene)-3a,5,7-tri-methyl-3,3a-dihydro-2H-indol-3-yl-idene]-2,4,6-trimethyl-aniline.

Mizuhata Yoshiyuki Y Tokitoh Norihiro N

Acta crystallographica. Section E, Structure reports online 20080123 Pt 2

The title compound, C(33)H(30)N(2), has an E configuration at the imine double bond. The angle between the least-squares planes of the imine C=N-C group and the benzene ring of the 2,4,6-trimethylphenyl substituent is 85.38 (11)°. The crystal structure is sustained mainly by inter-molecular π-π inter-actions (3.510 Å) between the two fluorene rings and some C-H⋯π inter-actions. ...[more]

PMID: 21201516

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