Unknown

Dataset Information

0

Bis(acetato-?O)[N,N,N',N'-tetra-methyl-ethane-1,2-diamine-?N,N']copper(II).


ABSTRACT: In the title compound, [Cu(C(2)H(3)O(2))(2)(C(6)H(16)N(2))], the Cu(II) atom is coordinated by two N atoms from the chelating N,N,N',N'-tetra-methyl-ethane-1,2-diamine ligand and two O atoms from two acetate anions in a distorted square-planar geometry. In addition, there are longer contacts between Cu and the second O atom of each acetate ligand, which could be considered to complete a distorted octa-hedral geometry. The mol-ecules in the crystal structure are connected via inter-molecular C-H?O hydrogen-bonding contacts.

SUBMITTER: Slootweg JC 

PROVIDER: S-EPMC2960195 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature

altmetric image

Publications

Bis(acetato-κO)[N,N,N',N'-tetra-methyl-ethane-1,2-diamine-κN,N']copper(II).

Slootweg J Chris JC   Chen Peter P  

Acta crystallographica. Section E, Structure reports online 20080130 Pt 2


In the title compound, [Cu(C(2)H(3)O(2))(2)(C(6)H(16)N(2))], the Cu(II) atom is coordinated by two N atoms from the chelating N,N,N',N'-tetra-methyl-ethane-1,2-diamine ligand and two O atoms from two acetate anions in a distorted square-planar geometry. In addition, there are longer contacts between Cu and the second O atom of each acetate ligand, which could be considered to complete a distorted octa-hedral geometry. The mol-ecules in the crystal structure are connected via inter-molecular C-H⋯  ...[more]

Similar Datasets

| S-EPMC3009181 | biostudies-literature
| S-EPMC3379114 | biostudies-literature
| S-EPMC2983213 | biostudies-literature
| S-EPMC3007970 | biostudies-literature
| S-EPMC2961079 | biostudies-literature
| S-EPMC3246975 | biostudies-literature
| S-EPMC2959593 | biostudies-literature
| S-EPMC3007037 | biostudies-literature
| S-EPMC3008138 | biostudies-literature
| S-EPMC2983616 | biostudies-literature