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Bis(acetato-?O)[N,N,N',N'-tetra-methyl-ethane-1,2-diamine-?N,N']copper(II).

ABSTRACT: In the title compound, [Cu(C(2)H(3)O(2))(2)(C(6)H(16)N(2))], the Cu(II) atom is coordinated by two N atoms from the chelating N,N,N',N'-tetra-methyl-ethane-1,2-diamine ligand and two O atoms from two acetate anions in a distorted square-planar geometry. In addition, there are longer contacts between Cu and the second O atom of each acetate ligand, which could be considered to complete a distorted octa-hedral geometry. The mol-ecules in the crystal structure are connected via inter-molecular C-H?O hydrogen-bonding contacts.

SUBMITTER: Slootweg JC

PROVIDER: S-EPMC2960195 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature

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Bis(acetato-κO)[N,N,N',N'-tetra-methyl-ethane-1,2-diamine-κN,N']copper(II).

Slootweg J Chris JC Chen Peter P

Acta crystallographica. Section E, Structure reports online 20080130 Pt 2

In the title compound, [Cu(C(2)H(3)O(2))(2)(C(6)H(16)N(2))], the Cu(II) atom is coordinated by two N atoms from the chelating N,N,N',N'-tetra-methyl-ethane-1,2-diamine ligand and two O atoms from two acetate anions in a distorted square-planar geometry. In addition, there are longer contacts between Cu and the second O atom of each acetate ligand, which could be considered to complete a distorted octa-hedral geometry. The mol-ecules in the crystal structure are connected via inter-molecular C-H⋯ ...[more]

PMID: 21201373

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