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Aqua-bis(2-chloro-acetato-?O)(1,10-phenanthroline-?N,N')copper(II).

ABSTRACT: In the title complex, [Cu(C(2)H(2)ClO(2))(2)(C(12)H(8)N(2))(H(2)O)], the Cu(II) ion is five-coordinated by two N atoms [Cu-N = 2.005?(2) and 2.029?(2)?Å] from the 1,10-phenanthroline ligand, two O atoms [Cu-O = 1.943?(2)-1.966?(2)?Å] from two 2-chloro-acetate ligands and one water mol-ecule [Cu-O = 2.253?(2)?Å] in a distorted square-pyramidal geometry. The crystal structure exhibits inter-molecular O-H?O hydrogen bonds, short Cl?Cl contacts [3.334?(1)?Å] and ?-? inter-actions [centroid-centroid distance 3.621?(11)?Å].

SUBMITTER: Yang R 

PROVIDER: S-EPMC2960263 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature

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Aqua-bis(2-chloro-acetato-κO)(1,10-phenanthroline-κN,N')copper(II).

Yang Rongdong R   Li Yanfei Y   Sun Junshan J   Li Jikun J   Chu Changqing C  

Acta crystallographica. Section E, Structure reports online 20080116 Pt 2

In the title complex, [Cu(C(2)H(2)ClO(2))(2)(C(12)H(8)N(2))(H(2)O)], the Cu(II) ion is five-coordinated by two N atoms [Cu-N = 2.005 (2) and 2.029 (2) Å] from the 1,10-phenanthroline ligand, two O atoms [Cu-O = 1.943 (2)-1.966 (2) Å] from two 2-chloro-acetate ligands and one water mol-ecule [Cu-O = 2.253 (2) Å] in a distorted square-pyramidal geometry. The crystal structure exhibits inter-molecular O-H⋯O hydrogen bonds, short Cl⋯Cl contacts [3.334 (1) Å] and π-π inter-actions [centroid-centroid  ...[more]

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