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(Acetato-?O,O')bis-(1,10-phenanthroline-?N,N')copper(II) trifluoro-acetate tetra-hydrate.

ABSTRACT: In the title compound, [Cu(CH(3)CO(2))(C(12)H(8)N(2))(2)](CF(3)CO(2))·4H(2)O, the Cu(II) atom shows a distorted octa-hedral coordination with four N atoms [Cu-N = 2.015?(3)-2.244?(3)?Å] from the two phenanthroline ligands and two O atoms from the acetate [Cu-O = 1.953?(3) and 2.764?(3)?Å]. Strong inter-molecular O-H?O hydrogen-bonding inter-actions consolidate the crystal packing. The F atoms of the anion are disordered over two positions in a 0.5233?(3):0.4767?(3) ratio.

SUBMITTER: Wang J 

PROVIDER: S-EPMC3007037 | biostudies-literature | 2010 Jun

REPOSITORIES: biostudies-literature

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(Acetato-κO,O')bis-(1,10-phenanthroline-κN,N')copper(II) trifluoro-acetate tetra-hydrate.

Wang Jinxia J   Jin Zhuping Z  

Acta crystallographica. Section E, Structure reports online 20100630 Pt 7

In the title compound, [Cu(CH(3)CO(2))(C(12)H(8)N(2))(2)](CF(3)CO(2))·4H(2)O, the Cu(II) atom shows a distorted octa-hedral coordination with four N atoms [Cu-N = 2.015 (3)-2.244 (3) Å] from the two phenanthroline ligands and two O atoms from the acetate [Cu-O = 1.953 (3) and 2.764 (3) Å]. Strong inter-molecular O-H⋯O hydrogen-bonding inter-actions consolidate the crystal packing. The F atoms of the anion are disordered over two positions in a 0.5233 (3):0.4767 (3) ratio. ...[more]

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