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Bis(methyl-ammonium) tetra-sulfido-tungstate(VI).

ABSTRACT: The title compound, (CH(6)N)(2)[WS(4)], was synthesized by the reaction of ammonium tetra-sulfidotungstate(VI) with aqueous methyl-amine. The title compound is isotypic with the corresponding Mo analogue (CH(6)N)(2)[MoS(4)], and its structure consists of a slightly distorted tetra-hedral [WS(4)](2-) dianion and two crystallographically independent methyl-ammonium (MeNH(3)) cations, all of which are located on crystallographic mirror planes. The tetra-sulfidotungstate anions are linked to the organic cations via hydrogen-bonding inter-actions.

SUBMITTER: Srinivasan BR

PROVIDER: S-EPMC2960287 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature

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Bis(methyl-ammonium) tetra-sulfido-tungstate(VI).

Srinivasan Bikshandarkoil R BR Näther Christian C Bensch Wolfgang W

Acta crystallographica. Section E, Structure reports online 20080104 Pt 2

The title compound, (CH(6)N)(2)[WS(4)], was synthesized by the reaction of ammonium tetra-sulfidotungstate(VI) with aqueous methyl-amine. The title compound is isotypic with the corresponding Mo analogue (CH(6)N)(2)[MoS(4)], and its structure consists of a slightly distorted tetra-hedral [WS(4)](2-) dianion and two crystallographically independent methyl-ammonium (MeNH(3)) cations, all of which are located on crystallographic mirror planes. The tetra-sulfidotungstate anions are linked to the org ...[more]

PMID: 21201273

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