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Bis(isopropyl-ammonium) tetra-sulfido-molybdate(VI).

ABSTRACT: The title compound, (C(3)H(10)N)(2)[MoS(4)], was synthesized by passing a rapid stream of H(2)S into an aqueous isopropyl-amine solution of molybdic acid. The title compound is isotypic with the corresponding W analogue (C(3)H(10)N)(2)[WS(4)]; its structure consists of a slightly distorted tetra-hedral [MoS(4)](2-) dianion and two crystallographically independent isopropyl-ammonium cations, with all atoms located in general positions. The cations and anion are linked by weak N-H⋯S and C-H⋯S inter-actions, the strength and number of which can explain the observed Mo-S bond distances.

SUBMITTER: Srinivasan BR

PROVIDER: S-EPMC2914947 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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Bis(isopropyl-ammonium) tetra-sulfido-molybdate(VI).

Srinivasan Bikshandarkoil R BR Näther Christian C Naik Ashish R AR Bensch Wolfgang W

Acta crystallographica. Section E, Structure reports online 20071206 Pt 1

The title compound, (C(3)H(10)N)(2)[MoS(4)], was synthesized by passing a rapid stream of H(2)S into an aqueous isopropyl-amine solution of molybdic acid. The title compound is isotypic with the corresponding W analogue (C(3)H(10)N)(2)[WS(4)]; its structure consists of a slightly distorted tetra-hedral [MoS(4)](2-) dianion and two crystallographically independent isopropyl-ammonium cations, with all atoms located in general positions. The cations and anion are linked by weak N-H⋯S and C-H⋯S inte ...[more]

PMID: 21200636

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