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Aqua-(3-formyl-2-oxidobenzoato-?O,O)(1,10-phenanthroline-?N,N')copper(II) methanol solvate.

ABSTRACT: In the structure of the title complex, [Cu(C(8)H(4)O(4))(C(12)H(8)N(2))(H(2)O)]·CH(4)O, the Cu(II) ion is penta-coordinated in a tetra-gonal-pyramidal geometry, with two O atoms of the 3-formyl-2-oxidobenzoate (3-formyl-salicylate) anion and two N atoms of 1,10-phenanthroline occupying the basal plane, and a water O atom located at the apical site. The structure displays O-H?O hydrogen bonding.

SUBMITTER: Zhang W

PROVIDER: S-EPMC2960304 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature

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Aqua-(3-formyl-2-oxidobenzoato-κO,O)(1,10-phenanthroline-κN,N')copper(II) methanol solvate.

Zhang Wu W Cui Qingxia Q Chang Ling L Yu Zhaowen Z

Acta crystallographica. Section E, Structure reports online 20080104 Pt 2

In the structure of the title complex, [Cu(C(8)H(4)O(4))(C(12)H(8)N(2))(H(2)O)]·CH(4)O, the Cu(II) ion is penta-coordinated in a tetra-gonal-pyramidal geometry, with two O atoms of the 3-formyl-2-oxidobenzoate (3-formyl-salicylate) anion and two N atoms of 1,10-phenanthroline occupying the basal plane, and a water O atom located at the apical site. The structure displays O-H⋯O hydrogen bonding. ...[more]

PMID: 21201271

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