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Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato-?N,O]cadmium(II) 1.75-hydrate.

ABSTRACT: In the title complex, [Cd(C(11)H(10)N(3)O(2))(2)]·1.75H(2)O, the Cd atom is coordinated by four N atoms and two O atoms from two tridentate 6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinate ligands in a distorted cis-N(4)O(2) octa-hedral geometry. Three water mol-ecules, with occupancies of 1.0, 0.5 and 0.25, complete the asymmetric unit. The components of the crystal structure are linked via hydrogen bonds, forming a three-dimensional network.

SUBMITTER: Kai Z

PROVIDER: S-EPMC2960373 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature

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Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato-κN,O]cadmium(II) 1.75-hydrate.

Kai Zhao Z Yin Xian-Hong XH Yu Feng F Zhu Jie J Lin Cui-Wu CW

Acta crystallographica. Section E, Structure reports online 20080130 Pt 2

In the title complex, [Cd(C(11)H(10)N(3)O(2))(2)]·1.75H(2)O, the Cd atom is coordinated by four N atoms and two O atoms from two tridentate 6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinate ligands in a distorted cis-N(4)O(2) octa-hedral geometry. Three water mol-ecules, with occupancies of 1.0, 0.5 and 0.25, complete the asymmetric unit. The components of the crystal structure are linked via hydrogen bonds, forming a three-dimensional network. ...[more]

PMID: 21201375

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